Tridec-2-en-1-ol

Base Information

• Chemical Name: Tridec-2-en-1-ol
• CAS No.: 68480-25-1
• Molecular Formula: C₁₃H₂₆O
• Molecular Weight: 198.349
• European Community (EC) Number: 270-902-9
• Wikidata: Q81999262
• Mol file: 68480-25-1.mol

Synonyms:tridec-2-en-1-ol;2-tridecene-1-ol;SY314200;FT-0641549

Chemical Property of Tridec-2-en-1-ol

Chemical Property:

• Melting Point: 28.6°C (estimate)
• Refractive Index: n20/D 1.455(lit.)
• Boiling Point: 278.6°Cat760mmHg
• PKA: 14.71±0.10(Predicted)
• Flash Point: 120.2°C
• PSA: 20.23000
• Density: 0.846g/cm³
• LogP: 4.06570
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 198.198365449
• Heavy Atom Count: 14
• Complexity: 118

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-2-Tridecen-1-ol >90.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCCCC=CCO

Technology Process of Tridec-2-en-1-ol

There total 44 articles about Tridec-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

AlH3.1/3 ethyl ether + ammonium chloride + ethyl (2E)-tridec-2-enoate (100586-27-4,136617-08-8) → trans-2-tridecenol (74962-98-4,68480-25-1)

Guidance literature:

In tetrahydrofuran;

Reference yield: 91.0%

tridec-2-yn-1-ol (51887-25-3) → trans-2-tridecenol (74962-98-4,68480-25-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 2h;

DOI:10.1016/S0040-4039(00)85233-8

Reference yield: 89.0%

[((E)-Tridec-2-enyl)oxymethyl]-benzene → trans-2-tridecenol (74962-98-4,68480-25-1)

Guidance literature:

With chromium dichloride; lithium iodide; In water; ethyl acetate; at 75 ℃; for 12h;

DOI:10.1002/1521-3773(20010401)40:7<1281::AID-ANIE1281>3.0.CO;2-B

upstream raw materials:

trimethylsilyloxirane

Phenyl undecyl sulfone

tridec-2-yn-1-ol

didecyl-1Z-dodecenylaluminum

Downstream raw materials:

(2S,3R,6S)-6-((1S,4S,5S)-1,4-bis(benzyloxy)-5-hydroxyhept-6-enyl)-2-decyl-3,6-dihydro-2H-pyran-3-ol

Refernces

• 1、 Nihei, Ken-Ichi,Hashimoto, Kimiko,Miyairi, Kazuo,Okuno, Toshikatsu. "Enantioselective synthesis of four isomers of 3-hydroxy-4- methyltetradecanoic acid, the constituent of antifungal cyclodepsipeptides W493 A and B". . p. 231 - 234. Retrieved 2005.
• 2、 Kan, Jian,Li, Chao-Jun,Li, Chen-Chen,Li, Jianbin,Lv, Leiyang,Qiu, Zihang. "Synergistic Relay Reactions To Achieve Redox-Neutral α-Alkylations of Olefinic Alcohols with Ruthenium(II) Catalysis". supporting information. p. 4544 - 4549. Retrieved 2020/02/04.
• 3、 Liu, Lihua,Bao, Xifei,Xiao, Hua,Li, Junlan,Ye, Feifan,Wang, Chaoqin,Cai, Qinhua,Fan, Shilu. "Copper-Catalyzed Perfluoroalkylation of Allyl Phosphates with Stable Perfluoroalkylzinc Reagents". . p. 423 - 434. Retrieved 2019/01/08.