(6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate

Base Information

Chemical Name:(6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate
CAS No.:81523-34-4
Molecular Formula:C₁₀H₁₄O₃
Molecular Weight:182.219
Hs Code.:
NSC Number:134989
DSSTox Substance ID:DTXSID901002024

Synonyms:81523-34-4;NSC134989;(6-oxobicyclo[2.2.1]heptan-2-yl)methyl acetate;SCHEMBL9593536;DTXSID901002024;NSC-134989

Suppliers and Price of (6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of (6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate

Chemical Property:

Vapor Pressure:0.00797mmHg at 25°C
Boiling Point:267.8°Cat760mmHg
Flash Point:114°C
Density:1.144g/cm³
XLogP3:0.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:182.094294304
Heavy Atom Count:13
Complexity:247

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1CC2CC1C(=O)C2

Technology Process of (6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate

There total 7 articles about (6-Oxobicyclo[2.2.1]heptan-2-yl)methyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 108-24-7
acetic anhydride

: 81523-31-1
6-endo-(Hydroxymethyl)bicyclo<2.2.1>heptan-2-one

: 81523-34-4
6-endo-(acetoxymethyl)-2-norbornanone

Guidance literature:: In pyridine; Ambient temperature;
DOI:10.1021/ja00378a033

Reference yield:

: 42392-37-0
(+/-)-6-oxobicyclo<2.2.1>heptane-endo-2-carboxylic acid

: 81523-34-4
6-endo-(acetoxymethyl)-2-norbornanone

Guidance literature:: Multi-step reaction with 4 steps

1: 78 percent / diethyl ether / Ambient temperature

2: 92 percent / p-toluenesulfonic acid / benzene / 6 h / Heating

3: 1.) lithium aluminum hydride, 2.) hydrochloric acid / 1.) ether, 4 h, 2.) room temperature, 3 h

4: 84 percent / pyridine / Ambient temperature

With hydrogenchloride; lithium aluminium tetrahydride; toluene-4-sulfonic acid; In pyridine; diethyl ether; benzene;
DOI:10.1021/ja00378a033

Reference yield:

: 15507-06-9
5-(hydroxymethyl)bicyclo[2.2.1]hept-2-ene

: 81523-34-4
6-endo-(acetoxymethyl)-2-norbornanone

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / iodine, triethylamine / methanol / 48 h / Heating

2: 8 percent Chromat_. / diethyl ether / 4 h / Irradiation

3: 73 percent Chromat_. / sulfuric acid / 2.5 h / Ambient temperature

4: 84 percent / pyridine / Ambient temperature

With sulfuric acid; iodine; triethylamine; In pyridine; methanol; diethyl ether;
DOI:10.1021/ja00378a033