Basketane

Base Information

Chemical Name:Basketane
CAS No.:5603-27-0
Molecular Formula:C10H12
Molecular Weight:132.2023
Hs Code.:
DSSTox Substance ID:DTXSID70891942
Nikkaji Number:J55.583E
Wikidata:Q791273
Wikipedia:Basketane
Mol file:5603-27-0.mol

Synonyms:Basketane;5603-27-0;DTXSID70891942;Q791273

Suppliers and Price of Basketane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Basketane

Chemical Property:

Vapor Pressure:0.984mmHg at 25°C
Boiling Point:184.8°Cat760mmHg
Flash Point:41.5°C
PSA：0.00000
Density:1.302g/cm³
LogP:1.76420
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:132.093900383
Heavy Atom Count:10
Complexity:198

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2C3C4C1C5C2C3C45

Technology Process of Basketane

There total 11 articles about Basketane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 57027-99-3
9-Cyanopentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decane

: 5603-27-0
Pentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decane

Guidance literature:: With methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; potassium; In diethyl ether; for 1h; Ambient temperature;
DOI:10.1021/jo01314a035

Reference yield: 23.6%

: 9-bromobasketane

: 5603-27-0
Pentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decane

: tricyclo<4.4.0.0^2,5>deca-3,8-diene

: tricyclo<4.4.0.0^2,5>deca-3,7-diene

Guidance literature:: With tri-n-butyl-tin hydride; at 212 ℃; for 0.583333h; Yields of byproduct given; Irradiation;

Reference yield:

: 10555-62-1
Pentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decane-9-one

: 5603-27-0
Pentacyclo<4.4.0.0^2,5.0^3,8.0^4,7>decane

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / LiAlH₄ / diethyl ether / 1.5 h / Heating

2: 75 percent / PPh₃, Br₂ / dimethylformamide / 0 - 20 °C

3: Bu₃SnH / 220 °C / Irradiation; E_r, log(A_r), var. temp.

With lithium aluminium tetrahydride; bromine; tri-n-butyl-tin hydride; triphenylphosphine; In diethyl ether; N,N-dimethyl-formamide;