6-Bromo-2-iodo-dibenzofuran

Base Information

• Chemical Name: 6-Bromo-2-iodo-dibenzofuran
• CAS No.: 916435-45-5
• Molecular Formula: C12H6BrIO
• Molecular Weight: 372.988
• Mol file: 916435-45-5.mol

Synonyms:6-bromo-2-iododibenzofuran;6-Bromo-2-iodo-dibenzofuran;

Chemical Property of 6-Bromo-2-iodo-dibenzofuran

Chemical Property:

• PSA: 13.14000
• LogP: 4.95310

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-Bromo-2-iodo-dibenzofuran

There total 2 articles about 6-Bromo-2-iodo-dibenzofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

4-bromodibenzofuran (89827-45-2) → 6-bromo-2-iododibenzo[b,d]furan (916435-45-5)

Guidance literature:

With [bis(acetoxy)iodo]benzene; sulfuric acid; iodine; acetic anhydride; acetic acid; at 20 ℃; for 36h; Inert atmosphere;

DOI:10.1039/c8tc04900a

Reference yield:

→ 6-bromo-2-iododibenzo[b,d]furan (916435-45-5)

Guidance literature:

Reference yield: 63.0%

6-bromo-2-iododibenzo[b,d]furan (916435-45-5) + 2-Biphenylboronic acid (4688-76-0) → 2-(biphenyl-2-yl)-6-bromodibenzo[b,d]furan

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; toluene; at 110 ℃; for 24h; Inert atmosphere;

upstream raw materials:

4-bromodibenzofuran

Refernces

• 1、 Jang, Seokhoon,Lee, Kyung Hyung,Lee, Jun Yeob,Lee, Youngu. "Dibenzo[: B, d] furan and dibenzo [b, d] thiophene molecular dimers as hole blocking materials for high-efficiency and long-lived blue phosphorescent organic light-emitting diodes". . p. 9599 - 9608. Retrieved 2019.
• 2、 -. "ORGANIC LIGHT EMITTING DIODE AND ORGANIC LIGHT EMITTING DEVICE HAVING THE SAME". Paragraph 0188-0189. . Retrieved 2020/05/06.