1-Cyclohexene-1-carboxylic acid, 3,4,6-tris(acetyloxy)-5-hydroxy-5-methyl-2-[1,4,5-tris(methoxymethoxy)-2 -naphthalenyl]-, (3S,4R,5R,6R)-

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Chemical Name:1-Cyclohexene-1-carboxylic acid, 3,4,6-tris(acetyloxy)-5-hydroxy-5-methyl-2-[1,4,5-tris(methoxymethoxy)-2 -naphthalenyl]-, (3S,4R,5R,6R)-
CAS No.:917113-20-3
Molecular Formula:C30H36O15
Molecular Weight:636.607
Hs Code.:

Synonyms:

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Chemical Property of 1-Cyclohexene-1-carboxylic acid, 3,4,6-tris(acetyloxy)-5-hydroxy-5-methyl-2-[1,4,5-tris(methoxymethoxy)-2 -naphthalenyl]-, (3S,4R,5R,6R)-

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Technology Process of 1-Cyclohexene-1-carboxylic acid, 3,4,6-tris(acetyloxy)-5-hydroxy-5-methyl-2-[1,4,5-tris(methoxymethoxy)-2 -naphthalenyl]-, (3S,4R,5R,6R)-

There total 10 articles about 1-Cyclohexene-1-carboxylic acid, 3,4,6-tris(acetyloxy)-5-hydroxy-5-methyl-2-[1,4,5-tris(methoxymethoxy)-2 -naphthalenyl]-, (3S,4R,5R,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₃₆O₁₄

: 917113-20-3
C₃₀H₃₆O₁₅

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; In water; tert-butyl alcohol; at 20 ℃; for 12h;
DOI:10.1021/ja066621v

Reference yield:

: 917113-23-6
C₁₇H₂₇BrO₆Si

: 917113-20-3
C₃₀H₃₆O₁₅

Guidance literature:: Multi-step reaction with 11 steps

1.1: 90 percent / Me₄NBH(OAc)3; AcOH / acetonitrile / 24 h / 0 °C

2.1: 85 percent / 2,4,6-collidine / CH₂Cl₂ / 8 h / 5 °C

3.1: 95 percent / Super-Hydride / 1,2-dichloro-ethane; tetrahydrofuran / 0.5 h / 60 °C

4.1: 90 percent / K-10 clay / CH₂Cl₂ / 4 h / 20 °C

5.1: 70 percent / AsPh₃; CuCl; DIEA / Pd₂(dba)3 / acetonitrile / 4 h / 70 °C

6.1: 80 percent / Super-Hydride / tetrahydrofuran / 1 h / -78 °C

7.1: Ti(iPrO)4 / CH₂Cl₂ / 0.5 h / 20 °C

7.2: 60 percent / CH₂Cl₂ / 10 h / 20 °C

8.1: 140 mg / pyridine / 2 h / 20 °C

9.1: 78 mg / Et₃N-3HF / acetonitrile / 12 h / 20 °C

10.1: 72 mg / N-methylmorpholine N-oxide / tetrapropylammonium perruthenate / CH₂Cl₂ / 0.33 h / 20 °C

11.1: 64 mg / NaClO₂; NaH₂PO₄ / 2-methyl-propan-2-ol; various solvent(s); H₂O / 12 h / 20 °C

With pyridine; 2,4,6-trimethyl-pyridine; titanium(IV) isopropylate; sodium chlorite; sodium dihydrogenphosphate; triphenyl-arsane; K-10 clay; lithium triethylborohydride; acetic acid; 4-methylmorpholine N-oxide; triethylamine tris(hydrogen fluoride); N-ethyl-N,N-diisopropylamine; copper(l) chloride; tetramethylammonium triacetoxyborohydride; tetrapropylammonium perruthennate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane; water; 1,2-dichloro-ethane; acetonitrile; tert-butyl alcohol; 5.1: Stille cross-coupling;
DOI:10.1021/ja066621v

Reference yield:

: 917113-28-1
C₁₈H₃₁BrO₈SiS

: 917113-20-3
C₃₀H₃₆O₁₅

Guidance literature:: Multi-step reaction with 9 steps

1.1: 95 percent / Super-Hydride / 1,2-dichloro-ethane; tetrahydrofuran / 0.5 h / 60 °C

2.1: 90 percent / K-10 clay / CH₂Cl₂ / 4 h / 20 °C

3.1: 70 percent / AsPh₃; CuCl; DIEA / Pd₂(dba)3 / acetonitrile / 4 h / 70 °C

4.1: 80 percent / Super-Hydride / tetrahydrofuran / 1 h / -78 °C

5.1: Ti(iPrO)4 / CH₂Cl₂ / 0.5 h / 20 °C

5.2: 60 percent / CH₂Cl₂ / 10 h / 20 °C

6.1: 140 mg / pyridine / 2 h / 20 °C

7.1: 78 mg / Et₃N-3HF / acetonitrile / 12 h / 20 °C

8.1: 72 mg / N-methylmorpholine N-oxide / tetrapropylammonium perruthenate / CH₂Cl₂ / 0.33 h / 20 °C

9.1: 64 mg / NaClO₂; NaH₂PO₄ / 2-methyl-propan-2-ol; various solvent(s); H₂O / 12 h / 20 °C

With pyridine; titanium(IV) isopropylate; sodium chlorite; sodium dihydrogenphosphate; triphenyl-arsane; K-10 clay; lithium triethylborohydride; 4-methylmorpholine N-oxide; triethylamine tris(hydrogen fluoride); N-ethyl-N,N-diisopropylamine; copper(l) chloride; tetrapropylammonium perruthennate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane; water; 1,2-dichloro-ethane; acetonitrile; tert-butyl alcohol; 3.1: Stille cross-coupling;
DOI:10.1021/ja066621v