3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)-

Base Information

Chemical Name:3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)-
CAS No.:917113-33-8
Molecular Formula:C30H38O14
Molecular Weight:622.623
Hs Code.:

Synonyms:

Suppliers and Price of 3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)-

There total 8 articles about 3-Cyclohexene-1,2,5,6-tetrol, 3-(hydroxymethyl)-1-methyl-4-[1,4,5-tris(methoxymethoxy)-2-naphthalen yl]-, 2,5,6-triacetate, (1R,2R,5S,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₆H₅₂O₁₄Si

: 917113-33-8
C₃₀H₃₈O₁₄

Guidance literature:: With triethylamine tris(hydrogen fluoride); In acetonitrile; at 20 ℃; for 12h;
DOI:10.1021/ja066621v

Reference yield:

: 917113-23-6
C₁₇H₂₇BrO₆Si

: 917113-33-8
C₃₀H₃₈O₁₄

Guidance literature:: Multi-step reaction with 9 steps

1.1: 90 percent / Me₄NBH(OAc)3; AcOH / acetonitrile / 24 h / 0 °C

2.1: 85 percent / 2,4,6-collidine / CH₂Cl₂ / 8 h / 5 °C

3.1: 95 percent / Super-Hydride / 1,2-dichloro-ethane; tetrahydrofuran / 0.5 h / 60 °C

4.1: 90 percent / K-10 clay / CH₂Cl₂ / 4 h / 20 °C

5.1: 70 percent / AsPh₃; CuCl; DIEA / Pd₂(dba)3 / acetonitrile / 4 h / 70 °C

6.1: 80 percent / Super-Hydride / tetrahydrofuran / 1 h / -78 °C

7.1: Ti(iPrO)4 / CH₂Cl₂ / 0.5 h / 20 °C

7.2: 60 percent / CH₂Cl₂ / 10 h / 20 °C

8.1: 140 mg / pyridine / 2 h / 20 °C

9.1: 78 mg / Et₃N-3HF / acetonitrile / 12 h / 20 °C

With pyridine; 2,4,6-trimethyl-pyridine; titanium(IV) isopropylate; triphenyl-arsane; K-10 clay; lithium triethylborohydride; acetic acid; triethylamine tris(hydrogen fluoride); N-ethyl-N,N-diisopropylamine; copper(l) chloride; tetramethylammonium triacetoxyborohydride; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; acetonitrile; 5.1: Stille cross-coupling;
DOI:10.1021/ja066621v

Reference yield:

: 917113-28-1
C₁₈H₃₁BrO₈SiS

: 917113-33-8
C₃₀H₃₈O₁₄

Guidance literature:: Multi-step reaction with 7 steps

1.1: 95 percent / Super-Hydride / 1,2-dichloro-ethane; tetrahydrofuran / 0.5 h / 60 °C

2.1: 90 percent / K-10 clay / CH₂Cl₂ / 4 h / 20 °C

3.1: 70 percent / AsPh₃; CuCl; DIEA / Pd₂(dba)3 / acetonitrile / 4 h / 70 °C

4.1: 80 percent / Super-Hydride / tetrahydrofuran / 1 h / -78 °C

5.1: Ti(iPrO)4 / CH₂Cl₂ / 0.5 h / 20 °C

5.2: 60 percent / CH₂Cl₂ / 10 h / 20 °C

6.1: 140 mg / pyridine / 2 h / 20 °C

7.1: 78 mg / Et₃N-3HF / acetonitrile / 12 h / 20 °C

With pyridine; titanium(IV) isopropylate; triphenyl-arsane; K-10 clay; lithium triethylborohydride; triethylamine tris(hydrogen fluoride); N-ethyl-N,N-diisopropylamine; copper(l) chloride; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; acetonitrile; 3.1: Stille cross-coupling;
DOI:10.1021/ja066621v