4,4',6,6'-tetranitro-2,2'-azoxytoluene

Base Information

• Chemical Name: 4,4',6,6'-tetranitro-2,2'-azoxytoluene
• CAS No.: 35212-01-2
• Molecular Formula: C₁₄H₁₀N₆O₉
• Molecular Weight: 406.268
• Hs Code.: 2927000090
• Mol file: 35212-01-2.mol

Synonyms:Diazene,bis(2-methyl-3,5-dinitrophenyl)-, 1-oxide (9CI);4,4',6,6'-Tetranitro-2,2'-azoxytoluene

Chemical Property of 4,4',6,6'-tetranitro-2,2'-azoxytoluene

Chemical Property:

• Vapor Pressure: 5.69E-15mmHg at 25°C
• Boiling Point: 627.3°Cat760mmHg
• Flash Point: 333.2°C
• PSA: 224.39000
• Density: 1.74g/cm³
• LogP: 6.47790

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4',6,6'-tetranitro-2,2'-azoxytoluene

There total 2 articles about 4,4',6,6'-tetranitro-2,2'-azoxytoluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-Hydroxylamino-4,6-dinitrotoluene (59283-76-0) → 4,4',6,6'-tetranitro-2,2'-azoxytoluene (35212-01-2)

Guidance literature:

Kinetics;

DOI:10.1021/es030010a

Reference yield:

→ 4,4',6,6'-tetranitro-2,2'-azoxytoluene (35212-01-2)

Guidance literature:

4,6-Dinitro-2-aminotoluol - Oxidation mit m-Chloroperbenzoesaeure;

DOI:10.1021/je60061a002

upstream raw materials:

2-Hydroxylamino-4,6-dinitrotoluene

Refernces

Chemical Reduction of 2,4,6-Trinitrotoluene - Initial Products

10.1021/je60061a002

The study focuses on the preparation of high-purity model compounds resulting from the reduction of 2,4,6-trinitrotoluene (TNT) for comparison with biodegradation products. The researchers aimed to produce 12 reduction products of TNT, including amino, hydroxylamino, azo, and azoxy compounds. They successfully synthesized eight compounds, two of which, 4,4',6,6'-tetranitro-2,2'-azoxytoluene and 2,4'-dimethyl-3,3',5,5'-tetranitro-ONN-azoxybenzene, are newly reported. The study details the preparation methods and improvements made in the purity of these compounds. Key chemicals involved include 2,4,6-trinitrotoluene (TNT) as the starting material, and various reagents such as m-chloroperoxybenzoic acid, ammonium sulfide, and sodium hypochlorite used in the reduction and oxidation processes to produce the desired compounds. The study also discusses the challenges and modifications made to existing methods to achieve high-purity products.