Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane

Base Information

Chemical Name:Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane
CAS No.:918138-96-2
Molecular Formula:C17H26OSi
Molecular Weight:274.478
Hs Code.:
DSSTox Substance ID:DTXSID40580033
Nikkaji Number:J2.404.242A

Synonyms:918138-96-2;Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane;DTXSID40580033

Suppliers and Price of Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:7
Exact Mass:274.175291983
Heavy Atom Count:19
Complexity:307

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCC=C=C(CC)O[Si](C)(C)C1=CC=CC=C1

Technology Process of Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane

There total 2 articles about Dimethyl[(nona-3,4-dien-3-yl)oxy]phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 693-02-7
hex-1-yne

: 918138-96-2
dimethyl(nona-3,4-dien-3-yloxy)(phenyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: ethylmagnesium bromide / diethyl ether; tetrahydrofuran / 1 h / 20 °C

1.2: 84 percent / diethyl ether; tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 90 percent / n-BuLi / tetrahydrofuran / 0 °C

With n-butyllithium; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; 2.1: 1,2-Brook process;
DOI:10.1021/ja0653674

Reference yield:

: 128084-44-6
1-(dimethyl(phenyl)silyl)propan-1-one

: 918138-96-2
dimethyl(nona-3,4-dien-3-yloxy)(phenyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: ethylmagnesium bromide / diethyl ether; tetrahydrofuran / 1 h / 20 °C

1.2: 84 percent / diethyl ether; tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 90 percent / n-BuLi / tetrahydrofuran / 0 °C

With n-butyllithium; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; 2.1: 1,2-Brook process;
DOI:10.1021/ja0653674

Reference yield: 18.0%

: 918138-96-2
dimethyl(nona-3,4-dien-3-yloxy)(phenyl)silane

: 15206-55-0
methyl 2-oxo-2-phenylacetate

: (E)-methyl 2-hydroxy-2-phenyl-3-propanoyloct-3-enoate

: (Z)-methyl 2-hydroxy-2-phenyl-3-propanoyloct-3-enoate

Guidance literature:: dimethyl(nona-3,4-dien-3-yloxy)(phenyl)silane; methyl 2-oxo-2-phenylacetate; scandium tris(trifluoromethanesulfonate); In dichloromethane; at -78 ℃;

With hydrogenchloride; In tetrahydrofuran; at 20 ℃;
DOI:10.1021/ja0653674