(1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone

Base Information

Chemical Name:(1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone
CAS No.:918403-11-9
Molecular Formula:C₁₂H₁₂O
Molecular Weight:172.227
Hs Code.:
DSSTox Substance ID:DTXSID10580025
Nikkaji Number:J2.389.896I

Synonyms:918403-11-9;(1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone;DTXSID10580025

Suppliers and Price of (1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:172.088815002
Heavy Atom Count:13
Complexity:248

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CC1=C)C(=O)C2=CC=CC=C2

Technology Process of (1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone

There total 2 articles about (1-Methyl-2-methylidenecyclopropyl)(phenyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 918403-05-1
1-methyl-2-methylene-cyclopropanecarbaldehyde

: 918403-11-9
(1-methyl-2-methylene-cyclopropyl)-phenyl-methanone

Guidance literature:: 1-methyl-2-methylene-cyclopropanecarbaldehyde; Phenyl-Mg-halide; In diethyl ether; at 0 ℃;

With dipyridinium dichromate; pyridinium trifluroacetate; In dichloromethane; at 20 ℃;
DOI:10.1016/j.tetlet.2006.09.124

Reference yield:

: 164665-65-0
tetrahydro-2-<1-(1-methyl-2-methylenecyclopropyl)methyloxy>-2H-pyran

: 918403-11-9
(1-methyl-2-methylene-cyclopropyl)-phenyl-methanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: TsOH / methanol

1.2: PDC / CH₂Cl₂ / 20 h / 20 °C

2.1: diethyl ether / 0 °C

2.2: PDC; pyridinium trifluoroacetate / CH₂Cl₂ / 20 °C

With toluene-4-sulfonic acid; In methanol; diethyl ether;
DOI:10.1016/j.tetlet.2006.09.124