Phosphine, methyl(2-methylphenyl)phenyl-

Base Information

• Chemical Name: Phosphine, methyl(2-methylphenyl)phenyl-
• CAS No.: 92621-97-1
• Molecular Formula: C₁₄H₁₅P
• Molecular Weight: 214.247
• DSSTox Substance ID: DTXSID90449267
• Nikkaji Number: J943.636G
• Mol file: 92621-97-1.mol

Synonyms:Phosphine, methyl(2-methylphenyl)phenyl-;92621-97-1;methylphenylo-tolylphosphine;Methyl o-tolylphenylphosphine;SCHEMBL4918290;DTXSID90449267;XPJXXVACCWDIFZ-UHFFFAOYSA-N

Chemical Property of Phosphine, methyl(2-methylphenyl)phenyl-

Chemical Property:

• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 214.091137476
• Heavy Atom Count: 15
• Complexity: 184

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=CC=C1P(C)C2=CC=CC=C2

Technology Process of Phosphine, methyl(2-methylphenyl)phenyl-

There total 36 articles about Phosphine, methyl(2-methylphenyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

P-methyl-P-phenyl-P-(ortho-tolyl)phosphine borane → (S)-methylphenyl(2-tolyl)phosphine (71779-60-7,92621-97-1,73622-07-8)

Guidance literature:

Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2019.05.015

Reference yield: 93.0%

methyllithium (917-54-4) + C20H20NP (202977-10-4) → (±)-methylphenyl-o-tolylphosphine (126180-52-7,71779-60-7,92621-97-1,73622-07-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

DOI:10.1039/a706428d

Reference yield: 90.0%

P-methyl-P-phenyl-P-(ortho-tolyl)phosphine oxide (71457-20-0,73303-65-8,92621-96-0,65523-10-6) → (±)-methylphenyl-o-tolylphosphine (126180-52-7,71779-60-7,92621-97-1,73622-07-8)

Guidance literature:

With lithium aluminium tetrahydride; cerium(III) chloride; In tetrahydrofuran; at 40 ℃; for 0.5h;

DOI:10.1246/cl.1985.1491

upstream raw materials:

P-methyl-P-phenyl-P-(ortho-tolyl)phosphine oxide

methyllithium

Dichlorophenylphosphine

(CH₃C₆H₄)2Cd

Downstream raw materials:

P-methyl-P-phenyl-P-(ortho-tolyl)phosphine oxide

(R_P)-methyl(phenyl)(o-tolyl)phosphine oxide

(C₆H₅)(CH₃C₆H₄)(CH₃)PCuI

(R_P)-methylphenyl(o-methylphenyl)phosphine