(3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol

Base Information

Chemical Name:(3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol
CAS No.:41410-53-1
Molecular Formula:C15H24O
Molecular Weight:220.35046
Hs Code.:
Mol file:41410-53-1.mol

Synonyms:(3aS,4S,8R,8aS,9S)-3a,4,8a-Trimethyl-7-methylene-decahydro-4,8-methano-azulen-9-ol;

Suppliers and Price of (3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of (3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol

Chemical Property:

PSA：20.23000
LogP:3.52990

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol

There total 14 articles about (3aS,9S)-Decahydro-3aβ,4,8aβ-trimethyl-7-methylene-4β,8β-methanoazulen-9-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 72312-12-0
2-((3aR,4R,8S,8aR,9S)-3a,4,8a-Trimethyl-7-methylene-decahydro-4,8-methano-azulen-9-yloxy)-tetrahydro-pyran

: 41410-53-1,71564-38-0
(+/-)-gymnomitrol

Guidance literature:: In tetrahydrofuran; water; acetic acid; at 60 ℃; for 7h;
DOI:10.1016/0040-4020(81)80018-X

Reference yield:

: 72312-09-5,72346-52-2
(4S,8R,9S)-9-Hydroxy-6-methoxy-3a,8,8a-trimethyl-2,3,3a,4,8,8a-hexahydro-1H-4,8-methano-azulen-5-one

: 41410-53-1,71564-38-0
(+/-)-gymnomitrol

Guidance literature:: Multi-step reaction with 5 steps

1: 59 percent / H₂ / Pd/C / ethanol / 1 h / 760 Torr / Ambient temperature

2: 54 mg / d-10-camphorsulfonic acid / CH₂Cl₂ / 1.) r. t., 1 h; 2.) 0 deg C, 2 h

3: 78 percent / Ca/liquid ammonia / tetrahydrofuran / 0.17 h

4: tetrahydrofuran; hexane; dimethylsulfoxide / 3.5 h / 80 °C

5: HOAc/H₂O / tetrahydrofuran / 7 h / 60 °C

With camphor-10-sulfonic acid; ammonia; water; hydrogen; calcium; acetic acid; palladium on activated charcoal; In tetrahydrofuran; ethanol; hexane; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/0040-4020(81)80018-X

Reference yield:

: 72312-13-1
(3aα,4α,8α,8aα,9R^*)-octahydro-3a,8,8a-trimethyl-9-<(tetrahydro-2H-pyran-2-yl)oxy>-4,8-methanoazulen-5(1H)-one

: 41410-53-1,71564-38-0
(+/-)-gymnomitrol

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran; hexane; dimethylsulfoxide / 3.5 h / 80 °C

2: HOAc/H₂O / tetrahydrofuran / 7 h / 60 °C

With water; acetic acid; In tetrahydrofuran; hexane; dimethyl sulfoxide;
DOI:10.1016/0040-4020(81)80018-X