7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-

Base Information

Chemical Name:7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-
CAS No.:932-03-6
Molecular Formula:C8H10O
Molecular Weight:122.167
Hs Code.:
DSSTox Substance ID:DTXSID60449077
Nikkaji Number:J611.446F

Synonyms:7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-;932-03-6;1-ethynyl-7-oxabicyclo[4.1.0]heptane;SCHEMBL1263212;DTXSID60449077

Suppliers and Price of 7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:122.073164938
Heavy Atom Count:9
Complexity:176

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C#CC12CCCCC1O2

Technology Process of 7-Oxabicyclo[4.1.0]heptane, 1-ethynyl-

There total 1 articles about 7-Oxabicyclo[4.1.0]heptane, 1-ethynyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 81447-34-9
2-(tosyloxy)cyclohexanone

: 4301-14-8
acetylenemagnesium bromide

: 932-03-6
1-Ethynyl-7-oxa-bicyclo[4.1.0]heptane

: 437608-12-3
toluene-4-sulfonic acid 2-ethynyl-2-hydroxy-cyclohexyl ester

Guidance literature:: In tetrahydrofuran; at -78 - 25 ℃; for 1h;
DOI:10.1021/ja012146j

Reference yield: 95.0%

: 932-03-6
1-Ethynyl-7-oxa-bicyclo[4.1.0]heptane

: 661-69-8
hexamethyldistannane

: C₆H₉(OH)CCHSn(CH₃)3

Guidance literature:: {Pd(C₆H₃(CH₂NMe₂)2-2,6)Br}; In tetrahydrofuran; alkyne and catalyst were dissolved in THF; to this mixt. was added Me3SnSnMe3; mixt. stirred at 0°C for 16 h; solvent evapd.; purified by column chromy.; rapid chromy. was applied;
DOI:10.1021/ja043951b