Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester

Base Information

Chemical Name:Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester
CAS No.:99423-49-1
Molecular Formula:C12H18O3
Molecular Weight:210.273
Hs Code.:
DSSTox Substance ID:DTXSID30465082
Nikkaji Number:J305.780A

Synonyms:99423-49-1;Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester;DTXSID30465082

Suppliers and Price of Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:210.125594432
Heavy Atom Count:15
Complexity:258

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1CCCC(C1=O)CC=C

Technology Process of Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester

There total 3 articles about Cyclohexanecarboxylic acid, 2-oxo-3-(2-propenyl)-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 106-95-6
allyl bromide

: 1655-07-8
ethyl 2-oxocyclohexane carboxylate

: 99423-49-1
ethyl 2-oxo-3-(2'-propenyl)cyclohexane-1-carboxylate

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at 0 ℃;
DOI:10.1016/S0040-4039(02)01214-5

Reference yield:

: 1655-07-8
ethyl 2-oxocyclohexane carboxylate

: 99423-49-1
ethyl 2-oxo-3-(2'-propenyl)cyclohexane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: p-toluenesulfonic acid monohydrate / benzene / 4.5 h / Heating

2: 2.) 5percent HCl / 1.) dioxane, reflux, 11 h, 2.) CHCl₃, 60 deg C, 5 h

With hydrogenchloride; toluene-4-sulfonic acid; In benzene;