1-(4-Methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethyl]tellanylethanone

Base Information

• Chemical Name: 1-(4-Methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethyl]tellanylethanone
• CAS No.: 99766-25-3
• Molecular Formula: C18H18O4Te
• Molecular Weight: 425.939
• DSSTox Substance ID: DTXSID90543996
• Nikkaji Number: J1.995.440D
• Wikidata: Q82420971
• Mol file: 99766-25-3.mol

Synonyms:99766-25-3;DTXSID90543996;2,2'-Tellanylbis[1-(4-methoxyphenyl)ethan-1-one]

Chemical Property of 1-(4-Methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethyl]tellanylethanone

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 428.0267318
• Heavy Atom Count: 23
• Complexity: 347

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(=O)C[Te]CC(=O)C2=CC=C(C=C2)OC

Technology Process of 1-(4-Methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethyl]tellanylethanone

There total 2 articles about 1-(4-Methoxyphenyl)-2-[2-(4-methoxyphenyl)-2-oxoethyl]tellanylethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

C18H18Br2O4Te (156540-86-2) → 1-(4-methoxy-phenyl)-2-[2-(4-methoxy-phenyl)-2-oxo-ethyltellanyl]-ethanone (99766-25-3)

Guidance literature:

With sodium metabisulfite; In dichloromethane;

DOI:10.1016/j.jorganchem.2003.10.021

Reference yield:

2-Bromo-4'-methoxyacetophenone (2632-13-5) → 1-(4-methoxy-phenyl)-2-[2-(4-methoxy-phenyl)-2-oxo-ethyltellanyl]-ethanone (99766-25-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Te / Heating

2: aq. Na₂S₂O₅ / CH₂Cl₂

With sodium metabisulfite; tellurium; In dichloromethane;

DOI:10.1080/10426500590906319

Reference yield: 80.0%

1-(4-methoxy-phenyl)-2-[2-(4-methoxy-phenyl)-2-oxo-ethyltellanyl]-ethanone (99766-25-3) → dichloro-bis-(4-methoxy-phenacyl)-λ4-tellane (66839-13-2)

Guidance literature:

With sulfuryl dichloride; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.jorganchem.2003.10.021

upstream raw materials:

C₁₈H₁₈Br₂O₄Te

2-Bromo-4'-methoxyacetophenone

Downstream raw materials:

dichloro-bis-(4-methoxy-phenacyl)-λ⁴-tellane

C₁₈H₁₈Br₂O₄Te

PdCl₂((CH₃OC₆H₄COCH₂)2Te)2