Methyl (Z)-8-methylnon-6-enoate

Base Information

Chemical Name:Methyl (Z)-8-methylnon-6-enoate
CAS No.:112375-42-5
Molecular Formula:C11H20 O2
Molecular Weight:184.279
Hs Code.:

Synonyms:Methyl (Z)-8-methylnon-6-enoate;112375-42-5;(Z)-Methyl 8-methylnon-6-enoate;(6Z)-8-Methyl-6-nonenoic Acid Methyl Ester;(Z)-Methyl8-methylnon-6-enoate

Suppliers and Price of Methyl (Z)-8-methylnon-6-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl (Z)-8-methylnon-6-enoate

Chemical Property:

Vapor Pressure:0.0744mmHg at 25°C
Boiling Point:228.2°Cat760mmHg
Flash Point:77°C
Density:0.887g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:184.146329876
Heavy Atom Count:13
Complexity:160

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C=CCCCCC(=O)OC
Isomeric SMILES:CC(C)/C=C\CCCCC(=O)OC

Technology Process of Methyl (Z)-8-methylnon-6-enoate

There total 5 articles about Methyl (Z)-8-methylnon-6-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 502-44-3,24980-41-4,80137-66-2
hexahydro-2H-oxepin-2-one

: 112375-42-5
methyl (6Z)-8-methylnon-6-enoate

Guidance literature:: Multi-step reaction with 3 steps

1: conc. H₂SO₄ / Heating

2: pyridinium chlorochromate (PCC), sodium acetate / CH₂Cl₂ / 1.5 h / Ambient temperature

3: 1.) t-BuOK / 1.) DMF, RT, 5 min, 2.) a) RT, 20 h, b) 90 deg C, 1 h

With sulfuric acid; potassium tert-butylate; sodium acetate; pyridinium chlorochromate; In dichloromethane;
DOI:10.1021/jo00240a024

Reference yield:

: 4547-43-7
methyl 6-hydroxycaproate

: 112375-42-5
methyl (6Z)-8-methylnon-6-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: pyridinium chlorochromate (PCC), sodium acetate / CH₂Cl₂ / 1.5 h / Ambient temperature

2: 1.) t-BuOK / 1.) DMF, RT, 5 min, 2.) a) RT, 20 h, b) 90 deg C, 1 h

With potassium tert-butylate; sodium acetate; pyridinium chlorochromate; In dichloromethane;
DOI:10.1021/jo00240a024

Reference yield:

: 598-23-2
3-methyl-but-1-yne

: C₁₄H₂₅BO₂

: 112375-42-5
methyl (6Z)-8-methylnon-6-enoate

Guidance literature:: With methanol; TriAgCl; lithium tert-butoxide; In 2,2,4-trimethylpentane; toluene; at 45 ℃; for 16h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jacs.9b09336