(1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol

Base Information

Chemical Name:(1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol
CAS No.:33947-55-6
Molecular Formula:C20H34O2
Molecular Weight:306.489
Hs Code.:
Mol file:33947-55-6.mol

Synonyms:torreferol;18-hydroxymanool;13-epi-torreferol;(13S)-Labda-8(17),14-dien-13β,18-diol;(R)-5-((1S,4aR,5R,8aR)-5-Hydroxymethyl-5,8a-dimethyl-2-methylene-decahydro-naphthalen-1-yl)-3-methyl-pent-1-en-3-ol;

Suppliers and Price of (1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of (1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol

Chemical Property:

Melting Point:152 - 154 °C
PSA：40.46000
LogP:4.47480

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol

There total 5 articles about (1S,4aα,αR)-Decahydro-α-vinyl-5α-(hydroxymethyl)-α,5,8aβ-trimethyl-2-methylene-1-naphthalene-1-propanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 596-85-0
manool

: 33947-55-6
Labda-8(17),14-dien-13β,18-diol

Guidance literature:: Multi-step reaction with 2 steps

1: Tween-60, α,α'-dipyridyl / 48 h / medium-A containing the bacterium JTS-162

2: LiAlH₄ / dioxane / 6 h / Heating

With [2,2]bipyridinyl; lithium aluminium tetrahydride; Tween-60; In 1,4-dioxane;
DOI:10.1080/00021369.1982.10865472

Reference yield:

: 596-85-0
manool

: 33947-55-6
Labda-8(17),14-dien-13β,18-diol

: 13β-Hydroxylabda-8(17),14-dien-18-al

: 83915-59-7
13β-Hydroxylabda-8(17),14-dien-18-oic acid

Guidance literature:: With [2,2]bipyridinyl; Tween-60; for 48h; medium-A containing the bacterium JTS-162;
DOI:10.1080/00021369.1982.10865472

Reference yield:

: 596-85-0
epimanool

: 1438-65-9,1908-44-7,3650-30-4,4549-12-6,33947-55-6,150134-40-0
labda-8(17),14-dien-13β,18-diol

Guidance literature:: Multi-step reaction with 2 steps

1: microbial transformation by Rhodococcus erythropolis JTS-131, 1.) (NH₄)2SO₄, K₂HPO₄, MgSO₄*7H₂O, CaCl₂*2H₂O, FeSO₄*7H₂O, Tween-60, 28 deg C, 12 h 2.) EDTA, 28 deg C, 48 h

2: LiAlH₄ / dioxane / 1 h / Heating

With lithium aluminium tetrahydride; In 1,4-dioxane;