BIS(2-CARBOXYPHENYL)DISELENIDE

Base Information

• Chemical Name: BIS(2-CARBOXYPHENYL)DISELENIDE
• CAS No.: 6512-83-0
• Molecular Formula: C14H10 O4 Se2
• Molecular Weight: 400.151
• Hs Code.: 2917399090
• NSC Number: 632603
• DSSTox Substance ID: DTXSID00215435
• Nikkaji Number: J87.207E
• Wikidata: Q83091484
• ChEMBL ID: CHEMBL1976884
• Mol file: 6512-83-0.mol

Synonyms:Benzoicacid, 2,2'-diselenodi- (6CI,7CI,8CI); 2,2'-Diselenobis[benzoic acid];2,2'-Diselenodibenzoic acid; Bis(2-carboxyphenyl) diselenide;Bis(o-carboxyphenyl) diselenide; NSC 632603

Chemical Property of BIS(2-CARBOXYPHENYL)DISELENIDE

Chemical Property:

• Melting Point: 297°C (rough estimate)
• Boiling Point: 585.7±60.0 °C(Predicted)
• PKA: 2.96±0.36(Predicted)
• Flash Point: 308oC
• PSA: 74.60000
• LogP: 0.35720
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 401.89095
• Heavy Atom Count: 20
• Complexity: 327

Purity/Quality:

99% ^*data from raw suppliers

BIS-(2-CARBOXYPHENYL)DISELENIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C(=O)O)[Se][Se]C2=CC=CC=C2C(=O)O

Technology Process of BIS(2-CARBOXYPHENYL)DISELENIDE

There total 29 articles about BIS(2-CARBOXYPHENYL)DISELENIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2,2'-diselanediyl-di-benzoic acid (6512-83-0)

Guidance literature:

anthranilic acid; With hydrogenchloride; sodium nitrite; In water; at 0 ℃; for 1h;

With disodium diselenide; at 20 ℃; for 120h;

DOI:10.1016/j.bmcl.2016.12.021

Reference yield: 98.0%

bis(2-carboxamidophenyl) diselenide (55038-90-9) → 2,2'-diselanediyl-di-benzoic acid (6512-83-0)

Guidance literature:

With potassium hydroxide; In water; for 22h; Ambient temperature;

DOI:10.1016/S0040-4020(01)89801-X

Reference yield: 90.0%

S-phenyl 2-[(phenylthio)seleno]benzoate (1441-91-4) → 2,2'-diselanediyl-di-benzoic acid (6512-83-0)

Guidance literature:

In water; for 24h;

DOI:10.1016/S0040-4020(02)00789-5

upstream raw materials:

o-Carboxybenzenediazonium

2-selenocyanato-benzoic acid

2-carboxybenzeneseleninic acid

ethyl 2-iodobenzoate

Downstream raw materials:

bis(2-methoxycarbonylphenyl) diselenide

2-(chloroseleno)benzoyl chloride

2,2’-diselanediyldibenzoyl chloride

2-selenono-benzoic acid