butanal, 2-acetyl-3-oxo-, compd. with 2,4-pentanedione, ruthenium salt (1:2:1)

Base Information

• Chemical Name: butanal, 2-acetyl-3-oxo-, compd. with 2,4-pentanedione, ruthenium salt (1:2:1)
• CAS No.: 76790-97-1
• Molecular Formula: C₁₆H₂₁O₇Ru
• Molecular Weight: 426.409
• Mol file: 76790-97-1.mol

Synonyms:Butanal, 2-acetyl-3-oxo-, ruthenium complex; NSC 368176

Chemical Property of butanal, 2-acetyl-3-oxo-, compd. with 2,4-pentanedione, ruthenium salt (1:2:1)

Chemical Property:

• Vapor Pressure: 1.07mmHg at 25°C
• Boiling Point: 176.8°Cat760mmHg
• Flash Point: 58.4°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of butanal, 2-acetyl-3-oxo-, compd. with 2,4-pentanedione, ruthenium salt (1:2:1)

There total 1 articles about butanal, 2-acetyl-3-oxo-, compd. with 2,4-pentanedione, ruthenium salt (1:2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(2,4-pentanedionato)ruthenium(III) (31378-26-4,31378-27-5,14284-93-6) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → (3-formylpentane-2,4-dionato)bis(pentane-2,4-dionato)ruthenium(III) (76790-97-1)

Guidance literature:

With sodium hydrogencarbonate; trichlorophosphate; In water; N,N-dimethyl-formamide; POCl3 slowly added to DMF and Ru(pd)3 in DMF added dropwise with stirring, react. mixt. warmed to room temp. and stirred for 4 h, ice/water slurry NaHCO3 slowly added and react. mixt. stirred for 14 h; soln. evapd. to dryness, residue dissolved in methanol and passed through silica gel column, using methanol as eluent, solvent. evapd.; elem. anal.;

upstream raw materials:

tris(2,4-pentanedionato)ruthenium(III)

N,N-dimethyl-formamide

Refernces