Fichtelite

Base Information

Chemical Name:Fichtelite
CAS No.:2221-95-6
Molecular Formula:C₁₉H₃₄
Molecular Weight:262.479
Hs Code.:
UNII:24ST878V9I
DSSTox Substance ID:DTXSID70176761
Nikkaji Number:J7.368G
Wikipedia:18-Norabietane,Fichtelite
Wikidata:Q4553717
Mol file:2221-95-6.mol

Synonyms:Fichtelite;2221-95-6;18-Norabietane;UNII-24ST878V9I;24ST878V9I;(2S,4aS,4bS,8S,8aS,10aS)-4b,8-dimethyl-2-propan-2-yl-2,3,4,4a,5,6,7,8,8a,9,10,10a-dodecahydro-1H-phenanthrene;Phenanthrene, tetradecahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1S,4aS,4bS,7S,8aS,10aS)-;Phenanthrene, tetradecahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1S-(1alpha,4aalpha,4bbeta,7beta,8aalpha,10abeta))-;Fichtelit;PHENANTHRENE, TETRADECAHYDRO-1,4A-DIMETHYL-7-(1-METHYLETHYL)-, (1S-(1.ALPHA.,4A.ALPHA.,4B.BETA.,7.BETA.,8A.ALPHA.,10A.BETA.))-;Phenanthrene, tetradecahydro-1,4a-dimethyl-7-(1-methylethyl)-, [1S-(1.alpha.,4a.alpha.,4b.beta.,7.beta.,8a.alpha.,10a.beta.)]-;FICHTELITE [MI];DTXSID70176761;(1S,4aS,4bS,7S,8aS,10aS)-7-Isopropyl-1,4a-dimethyltetradecahydrophenanthrene;HTNCYKZTYXSRHL-DYKIIFRCSA-N;C19H34;C19-H34;Q4553717;(1S,4AS,4BS,7S,8AS,10AS)-1,4A-DIMETHYL-7-(PROPAN-2-YL)-TETRADECAHYDROPHENANTHRENE;(1S,4aS,4bS,7S,8aS,10aS)-Tet-radecahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene;Phenanthrene, 1,2,3,4,4a,4b.alpha.,5,6,7,8,8a.beta.,9,10,10a.alpha.-tetradecahydro-7.alpha.-isopropyl-1.beta.,4a.beta.-dimethyl-, ()-

Suppliers and Price of Fichtelite

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
FICHTELITE 98.00%
5MG
$ 505.36

Total 4 raw suppliers

Chemical Property of Fichtelite

Chemical Property:

Vapor Pressure:0.000315mmHg at 25°C
Melting Point:45-46°
Refractive Index:nD20 1.5052
Boiling Point:330.6°Cat760mmHg
Flash Point:145.5°C
PSA：0.00000
Density:0.882g/cm³
LogP:5.91120
XLogP3:7.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:262.266051085
Heavy Atom Count:19
Complexity:318

Purity/Quality:

99% ^*data from raw suppliers

FICHTELITE 98.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CCCC2(C1CCC3C2CCC(C3)C(C)C)C
Isomeric SMILES:C[C@H]1CCC[C@]2([C@H]1CC[C@@H]3[C@@H]2CC[C@@H](C3)C(C)C)C

Technology Process of Fichtelite

There total 27 articles about Fichtelite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 74384-60-4
(4bS,10aS)-4b,8-Dimethyl-3,4,4a,4b,5,6,8a,9,10,10a-decahydro-2H-phenanthren-1-one

: 2221-95-6,19402-16-5,22343-29-9,94379-99-4
(1R,4aR,7R,8aR)-7-Isopropyl-1,4a-dimethyl-tetradecahydro-phenanthrene

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) LDA / 1.) THF, 5 min, 2.) 5 min

2: p-TsOH*H₂O / various solvent(s) / 0.17 h / Heating

3: 56 percent / CuI*Me₂S / diethyl ether / 0.08 h

4: i-Bu₂AlH / hexane / 5 h

5: 1.) SO₂Cl₂, pyridine, 2.) Me₂NH, 3.) Na, NH₃

6: H₂ / PtO₂ / acetic acid / 1 h

With pyridine; sulfuryl dichloride; copper(I) iodide dimethyl sulfide complex; ammonia; hydrogen; sodium; diisobutylaluminium hydride; toluene-4-sulfonic acid; dimethyl amine; lithium diisopropyl amide; platinum(IV) oxide; In diethyl ether; hexane; acetic acid;
DOI:10.1021/ja00535a046

Reference yield:

: 74384-60-4
(4bS,10aS)-4b,8-Dimethyl-3,4,4a,4b,5,6,8a,9,10,10a-decahydro-2H-phenanthren-1-one

: 2221-95-6,19402-16-5,22343-29-9,94379-99-4
(1S,4aR,7R,8aR)-7-Isopropyl-1,4a-dimethyl-tetradecahydro-phenanthrene

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) LDA / 1.) THF, 5 min, 2.) 5 min

2: p-TsOH*H₂O / various solvent(s) / 0.17 h / Heating

3: 56 percent / CuI*Me₂S / diethyl ether / 0.08 h

4: i-Bu₂AlH / hexane / 5 h

5: 1.) SO₂Cl₂, pyridine, 2.) Me₂NH, 3.) Na, NH₃

6: H₂ / PtO₂ / acetic acid / 1 h

With pyridine; sulfuryl dichloride; copper(I) iodide dimethyl sulfide complex; ammonia; hydrogen; sodium; diisobutylaluminium hydride; toluene-4-sulfonic acid; dimethyl amine; lithium diisopropyl amide; platinum(IV) oxide; In diethyl ether; hexane; acetic acid;
DOI:10.1021/ja00535a046

Reference yield:

: (2S,4bS,10aS)-2-Isopropyl-4b,8-dimethyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthren-1-ol

: 2221-95-6,19402-16-5,22343-29-9,94379-99-4
(1R,4aR,7R,8aR)-7-Isopropyl-1,4a-dimethyl-tetradecahydro-phenanthrene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) SO₂Cl₂, pyridine, 2.) Me₂NH, 3.) Na, NH₃

2: H₂ / PtO₂ / acetic acid / 1 h

With pyridine; sulfuryl dichloride; ammonia; hydrogen; sodium; dimethyl amine; platinum(IV) oxide; In acetic acid;
DOI:10.1021/ja00535a046