Hydroxymethyl-c-d2 radical

Base Information

• Chemical Name: Hydroxymethyl-c-d2 radical
• CAS No.: 79825-55-1
• Molecular Formula: CH3O
• Molecular Weight: 33.0183
• DSSTox Substance ID: DTXSID001000790
• Nikkaji Number: J788.338B

Synonyms:79825-55-1;Hydroxymethyl-c-d2 radical;CD2OH;Hydroxymethyl-d2 radical;Hydroxy(~2~H_2_)methyl;DTXSID001000790

Chemical Property of Hydroxymethyl-c-d2 radical

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: -0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 33.030943207
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2]O
• Isomeric SMILES: [2H][C]([2H])O

Technology Process of Hydroxymethyl-c-d2 radical

There total 2 articles about Hydroxymethyl-c-d2 radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1-trideuteromethanol (1849-29-2) + fluorine → dideuterio-hydroxy-methyl (79825-55-1) + dideuterio-deuteriooxy-methyl (6853-31-2) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + hydrogen fluoride (14333-26-7)

Guidance literature:

In gas; isothermal flow-reactor (295 K, 1.1-1.4 mbar, flow rate up to 44 m/s), F-atoms produced by microwave discharge (highly dild. F2/Ar mixt.), methanol/He mixt. by passing of He through double-stage saturator; mass spectrometry; Kinetics;

DOI:10.1002/bbpc.198800169

Reference yield:

1,1,1-trideuteromethanol (1849-29-2) → paraformaldehyde-d2 (1664-98-8,43094-80-0) + methane-d3 (676-80-2) + nitromethane-d3 (13031-32-8) + dideuterio-hydroxy-methyl (79825-55-1) + (2H3)-methyl nitrite (63562-23-2) + carbon dioxide (124-38-9,18923-20-1) + D2-nitrosomethanol

Guidance literature:

With nitrogen(II) oxide; Radiolysis;

DOI:10.1021/acs.jpca.7b12235

Reference yield:

dideuterio-hydroxy-methyl (79825-55-1) → paraformaldehyde-d2 (1664-98-8,43094-80-0)

Guidance literature:

With nitrogen(II) oxide; In gas; at 24.9 ℃; under 0.5 Torr; Product distribution; Rate constant; Thermodynamic data; Variation of temperature and pressure.;

DOI:10.1021/j100350a027

upstream raw materials:

1,1,1-trideuteromethanol

Downstream raw materials:

paraformaldehyde-d2

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