3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal

Base Information

Chemical Name:3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal
CAS No.:36518-11-3
Molecular Formula:C14H18O3
Molecular Weight:234.2909
Hs Code.:2914400090
UNII:5P42XHP9MY
Nikkaji Number:J17.600A
Wikipedia:Gyrinal
Wikidata:Q3122721
Metabolomics Workbench ID:3550
Mol file:36518-11-3.mol

Synonyms:gyrinidal;gyrinidal, (Z,E,E)-isomer

Suppliers and Price of 3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal

Chemical Property:

Vapor Pressure:3.99E-07mmHg at 25°C
Boiling Point:415.9°Cat760mmHg
Flash Point:179.9°C
PSA：51.21000
Density:1.011g/cm³
LogP:2.57240
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:7
Exact Mass:234.125594432
Heavy Atom Count:17
Complexity:384

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CC=O)CCC=C(C)C(=O)C=CC(=O)C
Isomeric SMILES:C/C(=C\C=O)/CC/C=C(\C)/C(=O)/C=C/C(=O)C

Technology Process of 3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal

There total 7 articles about 3,7-Dimethyl-8,11-dioxo-2E,6E,9E-dodecatrienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 41719-43-1
(2E,6E,9E)-3,7-dimethyl-dodeca-2,6,9-triene-1,8,11-triol

: 36518-11-3
(2E,6E,9E)-3,7-dimethyl-8,11-dioxo-dodeca-2,6,9-trienal

Guidance literature:: With manganese(IV) oxide; In chloroform; at 0 ℃;
DOI:10.1016/S0040-4039(01)95640-0

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 36518-11-3
(2E,6E,9E)-3,7-dimethyl-8,11-dioxo-dodeca-2,6,9-trienal

Guidance literature:: Multi-step reaction with 4 steps

1: SeO₂ / aq. ethanol / Heating

2: tetrahydrofuran

3: Na, liq. NH₃, EtOH / tetrahydrofuran

4: MnO₂ / CHCl₃ / 0 °C

With manganese(IV) oxide; selenium(IV) oxide; ethanol; ammonia; sodium; In tetrahydrofuran; ethanol; chloroform;
DOI:10.1016/S0040-4039(01)95640-0

Reference yield:

: 37905-02-5
(2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate

: 36518-11-3
(2E,6E,9E)-3,7-dimethyl-8,11-dioxo-dodeca-2,6,9-trienal

Guidance literature:: Multi-step reaction with 3 steps

1: tetrahydrofuran

2: Na, liq. NH₃, EtOH / tetrahydrofuran

3: MnO₂ / CHCl₃ / 0 °C

With manganese(IV) oxide; ethanol; ammonia; sodium; In tetrahydrofuran; chloroform;
DOI:10.1016/S0040-4039(01)95640-0