1-(4-(Phenylazo)phenyl)pyrrolidine

Base Information

• Chemical Name: 1-(4-(Phenylazo)phenyl)pyrrolidine
• CAS No.: 10282-34-5
• Molecular Formula: C₁₆H₁₇N₃
• Molecular Weight: 251.331
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID101037742
• Nikkaji Number: J126.011A
• Mol file: 10282-34-5.mol

Synonyms:4-N-pyrrolidinylazobenzene

Chemical Property of 1-(4-(Phenylazo)phenyl)pyrrolidine

Chemical Property:

• Vapor Pressure: 2.33E-07mmHg at 25°C
• Boiling Point: 422.9°Cat760mmHg
• Flash Point: 209.6°C
• PSA: 27.96000
• Density: 1.11g/cm³
• LogP: 4.76720
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 251.142247555
• Heavy Atom Count: 19
• Complexity: 282

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-N-PYRROLIDINYLAZOBENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCN(C1)C2=CC=C(C=C2)N=NC3=CC=CC=C3

Technology Process of 1-(4-(Phenylazo)phenyl)pyrrolidine

There total 4 articles about 1-(4-(Phenylazo)phenyl)pyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aniline (62-53-3) → Phenyl-(4-pyrrolidin-1-yl-phenyl)-diazene (10282-34-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent

2: 1.) NaNO₂, H⁽¹⁺⁾, 2.) sodium acetate / 2.) H₂O, 2.) acetic acid, 0 deg C, 3 h

With sodium acetate; hydrogen cation; sodium nitrite;

Reference yield:

N-phenylpyrrolidine (4096-21-3) + aniline (62-53-3) → 4-Pyrrolidinoazobenzol (10282-34-5)

Guidance literature:

With hydrogenchloride; sodium hydroxide; sodium nitrite;

Reference yield:

N-phenylpyrrolidine (4096-21-3) + aniline (62-53-3) → Phenyl-(4-pyrrolidin-1-yl-phenyl)-diazene (10282-34-5)

Guidance literature:

With sodium acetate; hydrogen cation; sodium nitrite; Multistep reaction; 2.) H₂O, 2.) acetic acid, 0 deg C, 3 h;

upstream raw materials:

N-phenylpyrrolidine

aniline

Refernces

• 1、 Hallas, Geoffrey,Marsden, Richard,Hepworth, John D.,Mason, Donald. "THE EFFECTS OF CYCLIC TERMINAL GROUPS IN 4-AMINOAZOBENZENE AND RELATED AZO DYES. PART 1. ELECTRONIC ABSORPTION SPECTRA OF SOME MONOAZO DYES DERIVED FROM N-PHENYLPYRROLIDINE AND N-PHENYLPIPERIDINE". . p. 149 - 154. Retrieved 2007/10/02.