Thioglycolate(2-)

Base Information

• Chemical Name: Thioglycolate(2-)
• CAS No.: 16561-17-4
• Molecular Formula: C2H2 O2 S
• Molecular Weight: 92.12
• DSSTox Substance ID: DTXSID301304062
• Wikidata: Q27120832
• Mol file: 16561-17-4.mol

Synonyms:Thioglycolate(2-);2-sulfidoacetate;16561-17-4;Acetic acid, mercapto, ion(2-);sulfidoacetate;mercaptoacetic acid, ion(2-);CHEBI:47869;DTXSID301304062;Acetic acid, mercapto-, ion(2-);Q27120832

Chemical Property of Thioglycolate(2-)

Chemical Property:

• Vapor Pressure: 0.0314mmHg at 25°C
• Boiling Point: 225.5°C at 760 mmHg
• Flash Point: 99.8°C
• Density: 1.311g/cm³
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 89.97755048
• Heavy Atom Count: 5
• Complexity: 37.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(=O)[O-])[S-]

Technology Process of Thioglycolate(2-)

There total 4 articles about Thioglycolate(2-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{MoO(SCH2CO2)2}(2-) → MoO(SCH2CO2)(OH2)2 + thioglycolate dianion (16561-17-4)

Guidance literature:

With H₂O; In methanol; (Ar); room temp.; methanol contg. (Bu4N)(PF6) used as solvent; equil. exists under cyclovoltammetric conditions; presence of the two Mo species derived from cyclovoltammetric studies;

DOI:10.1039/DT9940000175

Reference yield:

C5H10NO2S(1-) (1060936-14-2) + CH3HgSCH2COO(1-) → thioglycolate dianion (16561-17-4) + methylmercury-D,L-penicillaminate

Guidance literature:

In water; react. methylmercury(II)-mercaptoacetic acid complex with penicillaminein aq. soln.; not isolated; Kinetics;

Reference yield:

OOCCH(NH3)CH2CH2CONHCH(CH2S)CONHCH2COO(2-) + CH3HgSCH2COO(1-) → OOCCH(NH3)CH2CH2CONHCH(CH2SHgCH3)CONHCH2COO(1-) + thioglycolate dianion (16561-17-4)

Guidance literature:

In water; react. methylmercury(II)-mercaptoacetic acid complex with glutathione in aq. soln.; not isolated; Kinetics;

upstream raw materials:

C₅H₁₀NO₂S^(1-)

C₃H₆NO₂S^(1-)

Downstream raw materials:

(3-Chloro-4-methanesulfonyl-phenylsulfanyl)-acetic acid