Tetrafluorosuccinyl chloride

Base Information

• Chemical Name: Tetrafluorosuccinyl chloride
• CAS No.: 356-15-0
• Molecular Formula: C4Cl2 F4 O2
• Molecular Weight: 226.942
• Hs Code.: 2917190090
• European Community (EC) Number: 206-598-1
• DSSTox Substance ID: DTXSID00189066
• Nikkaji Number: J193.848G
• Mol file: 356-15-0.mol

Synonyms:Tetrafluorosuccinyl chloride;356-15-0;Tetrafluorosuccinyl dichloride;2,2,3,3-tetrafluorobutanedioyl dichloride;TETRAFLUOROSUCCINYLCHLORIDE;C4Cl2F4O2;EINECS 206-598-1;MFCD00013653;2,2,3,3-Tetrafluorosuccinyl dichloride;Perfluorosuccinyl chloride;SCHEMBL1599019;C4-Cl2-F4-O2;DTXSID00189066;Tetrafluorosuccinic acid dichloride;Butanedioyl dichloride, tetrafluoro-;AKOS015852895;Tetrafluorobutane-1,4-dioyl dichloride;Tetrafluorosuccinyl chloride, AldrichCPR;BS-27997;FT-0632030;1,4-Dichloro-2,2,3,3-tetrafluorobutane-1,4-dione

Chemical Property of Tetrafluorosuccinyl chloride

Chemical Property:

• Vapor Pressure: 15.5mmHg at 25°C
• Boiling Point: 120.1°Cat760mmHg
• Flash Point: 26.4°C
• PSA: 34.14000
• Density: 1.7g/cm³
• LogP: 1.78780
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 225.9211473
• Heavy Atom Count: 12
• Complexity: 203

Purity/Quality:

98%min ^*data from raw suppliers

TetrafluorosuccinylChloride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(C(=O)Cl)(F)F)(F)F)Cl
• Uses: Tetrafluorosuccinyl Chloride is a useful compound for organic reactions and synthesis.

Technology Process of Tetrafluorosuccinyl chloride

There total 9 articles about Tetrafluorosuccinyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

perfluorosuccinic difluoride (679-13-0) → tetrafluorosuccinyl chloride (356-15-0) + Tetrafluorobutanedioyl bromide chloride + Tetrafluorobutanedioyl dibromide

Guidance literature:

With lithium chloride; lithium bromide; at 250 ℃; for 24h; Yields of byproduct given;

DOI:10.1039/p19960000915

Reference yield: 41.0%

perfluorosuccinic difluoride (679-13-0) → tetrafluorosuccinyl chloride (356-15-0) + Tetrafluorobutanedioyl chloride fluoride + Tetrafluorobutanedioyl chloride iodide + Tetrafluorobutanedioyl diiodide

Guidance literature:

With lithium chloride; lithium iodide; at 80 ℃; for 90h; Further byproducts given. Yields of byproduct given;

DOI:10.1039/p19960000915

Reference yield: 25.0%

perfluorosuccinic difluoride (679-13-0) → tetrafluorosuccinyl chloride (356-15-0) + Tetrafluorobutanedioyl chloride fluoride

Guidance literature:

With lithium chloride; at 330 ℃; for 5h;

DOI:10.1039/p19960000915

upstream raw materials:

tetrafluorosuccinic acid

perfluorosuccinic difluoride

1,2-dichloro-3,3,4,4-tetrafluorocyclobutene

Downstream raw materials:

tetrafluorosuccinic acid

2,2,3,3-tetrafluorobutane-1,4-diol

Perfluorbernsteinsaeure-diphenylester

perfluorosuccinic difluoride

Refernces

• 1、 -. "Preparation method of fluorine-containing carboxylic acid". Paragraph 0033-0034; 0036. . Retrieved 2020/07/12.