3-Methylphenylbutyl sulfide

Base Information

• Chemical Name: 3-Methylphenylbutyl sulfide
• CAS No.: 54576-41-9
• Molecular Formula: C11H16S
• Molecular Weight: 180.3097
• Mol file: 54576-41-9.mol

Synonyms:3-Methylphenylbutyl sulfide;

Chemical Property of 3-Methylphenylbutyl sulfide

Chemical Property:

• Vapor Pressure: 0.0233mmHg at 25°C
• Boiling Point: 257.5°Cat760mmHg
• Flash Point: 107.4°C
• PSA: 25.30000
• Density: 0.96g/cm³
• LogP: 3.88720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Methylphenylbutyl sulfide

There total 2 articles about 3-Methylphenylbutyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

n-butanethiol (109-79-5) + 3-Iodotoluene (625-95-6) → 1-(Butylthio)-3-methyl-benzene (54576-41-9)

Guidance literature:

With caesium carbonate; 2-(diphenylphosphinyl)-benzaldoxime; copper(l) iodide; In N,N-dimethyl-formamide; at 90 ℃; for 24h;

DOI:10.1016/j.tetlet.2006.05.178

Reference yield:

1-iodo-butane (542-69-8) + toluene-3-thiol (108-40-7) → 1-(Butylthio)-3-methyl-benzene (54576-41-9)

Guidance literature:

toluene-3-thiol; With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 0.166667h; Inert atmosphere;

1-iodo-butane; In N,N-dimethyl-formamide; Inert atmosphere; Reflux;

DOI:10.1039/c9cc06535k

upstream raw materials:

n-butanethiol

3-Iodotoluene

1-iodo-butane

toluene-3-thiol

Refernces

• 1、 Wang, Haolong,Wan, Boshun. "Cu-catalyzed coupling of aryl iodides with thiols using carbonyl-phosphine oxide ligands". scheme or table. p. 1129 - 1132. Retrieved 2012/06/18.
• 2、 Zhu, Di,Xu, Lei,Wu, Fan,Wan, Boshun. "A mild and efficient copper-catalyzed coupling of aryl iodides and thiols using an oxime-phosphine oxide ligand". . p. 5781 - 5784. Retrieved 2007/10/03.