14-Methoxy-19-methyl-5,7-dioxa-19-azapentacyclo[9.7.2.02,10.04,8.012,17]icosa-2,4(8),9,12,14,16-hexaen-15-ol

Base Information

• Chemical Name: 14-Methoxy-19-methyl-5,7-dioxa-19-azapentacyclo[9.7.2.02,10.04,8.012,17]icosa-2,4(8),9,12,14,16-hexaen-15-ol
• CAS No.: 10481-92-2
• Molecular Formula: C₁₉H₁₉NO₄
• Molecular Weight: 325.364
• Wikidata: Q104965831
• Mol file: 10481-92-2.mol

Synonyms:

Chemical Property of 14-Methoxy-19-methyl-5,7-dioxa-19-azapentacyclo[9.7.2.02,10.04,8.012,17]icosa-2,4(8),9,12,14,16-hexaen-15-ol

Chemical Property:

• Vapor Pressure: 4.87E-09mmHg at 25°C
• Boiling Point: 458.8°Cat760mmHg
• Flash Point: 231.3°C
• PSA: 51.16000
• Density: 1.328g/cm³
• LogP: 2.74190
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 1
• Exact Mass: 325.13140809
• Heavy Atom Count: 24
• Complexity: 488

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN1CC2C3=CC4=C(C=C3C1CC5=CC(=C(C=C25)OC)O)OCO4

Technology Process of 14-Methoxy-19-methyl-5,7-dioxa-19-azapentacyclo[9.7.2.02,10.04,8.012,17]icosa-2,4(8),9,12,14,16-hexaen-15-ol

There total 1 articles about 14-Methoxy-19-methyl-5,7-dioxa-19-azapentacyclo[9.7.2.02,10.04,8.012,17]icosa-2,4(8),9,12,14,16-hexaen-15-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-(3-benzyloxy-4-methoxy-benzyl)-6-methyl-[1,3]dioxolo[4,5-g]isoquinolinium; iodide (53811-60-2) → Amurensin (10481-92-2,38699-64-8)

Guidance literature:

Multistep reaction; (i) LiAlH₄, (ii) B₂H₆, THF, (iii) aq. H₂O₂, NaOH;

DOI:10.1016/S0040-4020(01)93845-1

upstream raw materials:

5-(3-benzyloxy-4-methoxy-benzyl)-6-methyl-[1,3]dioxolo[4,5-g]isoquinolinium; iodide