CID 11001507

Base Information

• Chemical Name: CID 11001507
• CAS No.: 13257-51-7
• Molecular Formula: C4F6HgO4
• Molecular Weight: 426.622
• Hs Code.: 29159080
• Mol file: 13257-51-7.mol

Synonyms:

Chemical Property of CID 11001507

Chemical Property:

• Appearance/Colour: almost white to light beige crystalline powder
• Vapor Pressure: 96.2mmHg at 25°C
• Melting Point: 171-173 °C(lit.)
• Boiling Point: 72.2 °C at 760 mmHg
• PSA: 52.60000
• LogP: 1.10990
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 315.963507
• Heavy Atom Count: 8
• Complexity: 87.8

Purity/Quality:

99% ^*data from raw suppliers

Mercury(II) trifluoroacetate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+, N, T
• Hazard Codes: T+,N,T
• Statements: 26/27/28-33-50/53-50-28
• Safety Statements: 13-28-36-45-60-61-28A-26-22-20

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(F)(F)F)O.[Hg]
• Uses: Mercuric Trifluoroacetate can be used to prepare shrinkage-?reducing polycarboxylic acid water reducer for concrete.

Technology Process of CID 11001507

There total 5 articles about CID 11001507 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trifluoroacetic acid (76-05-1) + mercury(II) oxide (12653-71-3) → mercury(II) trifluoroacetate (13257-51-7)

Guidance literature:

at 80 ℃; for 0.5h;

DOI:10.15227/orgsyn.061.0048

Reference yield:

mercury(I) trifluoroacetate → mercury(II) trifluoroacetate (13257-51-7) + mercury(I) chloride (104923-33-3)

Guidance literature:

With HCl; In trifluoroacetic acid;

DOI:10.1021/ja01567a026

Reference yield:

trifluoroacetyl hypobromite (431-45-8) + C2F3O2(1-)*Br(1-)*Hg(2+) → mercury(II) trifluoroacetate (13257-51-7)

Guidance literature:

In trifluoroacetic acid; at 25 ℃; Equilibrium constant;

DOI:10.1021/ja00772a034

upstream raw materials:

trifluoroacetyl hypobromite

Trifluoracetylhypoiodit

trifluoroacetic acid

mercury(II) oxide

Downstream raw materials:

phenylmercury(II) trifluoroacetate

3-bromo-1-phenylpropyl tert-butyl peroxide

iodotrifluoromethane

(2,3,4,5,6-pentamethylphenyl)(2,2,2-trifluoroacetoxy)mercury

Refernces

• 1、 Barnett,J.R. et al.. "-". . p. 6129 - 6134. Retrieved 1972.
• 2、 Humphries, R. E.,Massey, A. G.. "A New Type of Selenium Heterocycle: Tetrachlorobenzo-1,2,3-Triselenole". . p. 135 - 138. Retrieved 2007/10/02.