cobalt(2+) bis[(2-hydroxybenzylidene)azanide]

Base Information

• Chemical Name: cobalt(2+) bis[(2-hydroxybenzylidene)azanide]
• CAS No.: 14220-45-2
• Molecular Formula: C₁₄H₁₂CoN₂O₂
• Molecular Weight: 299.255
• DSSTox Substance ID: DTXSID60329825
• Mol file: 14220-45-2.mol

Synonyms:Cobalt,bis(o-formimidoylphenolato)- (7CI,8CI); Phenol, 2-(iminomethyl)-, cobaltcomplex; Bis(salicylaldiminato)cobalt; NSC 162801

Chemical Property of cobalt(2+) bis[(2-hydroxybenzylidene)azanide]

Chemical Property:

• Vapor Pressure: 0.126mmHg at 25°C
• Boiling Point: 211.4°Cat760mmHg
• Flash Point: 81.6°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 299.023071
• Heavy Atom Count: 19
• Complexity: 103

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C=[N-])O.C1=CC=C(C(=C1)C=[N-])O.[Co+2]

Technology Process of cobalt(2+) bis[(2-hydroxybenzylidene)azanide]

There total 5 articles about cobalt(2+) bis[(2-hydroxybenzylidene)azanide] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Co(OC6H4CHNH)2}*2H2O → bis(N-salicylaldimino) Co(II) (14220-45-2)

Guidance literature:

In neat (no solvent); heating in vac. delivers 2 mol H2O under formation of (Co(OC6H4CHNH)2);;

DOI:10.1021/ja01200a013

Reference yield:

2-(iminomethyl)phenol (3117-61-1) → bis(N-salicylaldimino) Co(II) (14220-45-2)

Guidance literature:

Multi-step reaction with 2 steps

1: water; ethanol

2: neat (no solvent)

In ethanol; water;

DOI:10.1021/ja01200a013

Reference yield:

salicylaldehyde-ammonia → bis(N-salicylaldimino) Co(II) (14220-45-2)

Guidance literature:

Multi-step reaction with 2 steps

1: NH₃ / water; ethanol

2: neat (no solvent)

With NH₃; In ethanol; water;

upstream raw materials:

ammonia

cobalt(II)

salicylaldehyde

2-(iminomethyl)phenol