5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester

Base Information

Chemical Name:5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester
CAS No.:28487-86-7
Molecular Formula:C₂₁H₂₆O₆
Molecular Weight:374.434
Hs Code.:
Mol file:28487-86-7.mol

Synonyms:17-Norlabda-1(10),13(16),14-trien-18(or19)-oic acid, 15,16-epoxy-5-hydroxy-9-methyl-2,12-dioxo-, methyl ester (8CI);(-)-Chettaphanin I; Chettaphanin I

Suppliers and Price of 5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 11 raw suppliers

Chemical Property of 5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of 5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester

There total 3 articles about 5-[2-(3-Furyl)-2-oxoethyl]-1,2,3,5,6,7,8,8a-octahydro-8a-hydroxy-1,5,6-trimethyl-3-oxo-1-naphthalenecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 518034-92-9
methyl 5α,10α-15,16-diepoxy-2-ethylenedioxy-12-oxo-13(16),14-ent-halimandien-18-oate

: methyl 5α,10α-epoxy-2,12-dioxo-13(16),14-ent-halimandien-18-oate

: 28487-86-7
chettaphanin I

: methyl (10S,12S)-10,12-15,16-diepoxy-5α,12-dihydroxy-2-oxo-13(16),14-ent-halimandien-18-oate

Guidance literature:: With perchloric acid; In N,N-dimethyl-formamide; for 3h;
DOI:10.1016/S0040-0(02)01564-8

Reference yield:

: 437703-38-3
methyl 15,16-epoxy-2-ethylendioxy-12SR-hydroxy-5⁽¹⁰⁾,13⁽¹⁶⁾,14-ent-halimatrien-18-oate

: 28487-86-7
chettaphanin I

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / N-methylmorpholine N-oxide; TPAP; molecular sieves / CH₂Cl₂ / 0.5 h / 20 °C

2: 92 percent / m-CPBA / CH₂Cl₂ / 12 h / 20 °C

3: 30 percent / 63 percent HClO₄ / dimethylformamide / 3 h

With perchloric acid; molecular sieve; tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-0(02)01564-8

Reference yield:

: 437703-39-4
methyl 15,16-epoxy-2-ethylenedioxy-12-oxo-5⁽¹⁰⁾,13⁽¹⁶⁾,14-ent-halimatrien-18-oate

: 28487-86-7
chettaphanin I

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / m-CPBA / CH₂Cl₂ / 12 h / 20 °C

2: 30 percent / 63 percent HClO₄ / dimethylformamide / 3 h

With perchloric acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-0(02)01564-8