beta-D-tagatopyranose

Base Information

Chemical Name:beta-D-tagatopyranose
CAS No.:20197-42-6
Molecular Formula:C6H12 O6
Molecular Weight:180.158
Hs Code.:
UNII:VVT3718CT7
Metabolomics Workbench ID:57206
Nikkaji Number:J1.057.973B
Wikidata:Q27121478

Synonyms:beta-D-tagatopyranose;VVT3718CT7;UNII-VVT3718CT7;20197-42-6;D-lyxo-hex-2-ulose;D-lyxo-2-Hexulose;.BETA.-D-TAGATOPYRANOSE;SCHEMBL17038724;CHEBI:49092;Q27121478;(2R,3S,4S,5R)-2-(Hydroxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetraol

Suppliers and Price of beta-D-tagatopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of beta-D-tagatopyranose

Chemical Property:

XLogP3:-2.8
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:180.06338810
Heavy Atom Count:12
Complexity:162

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(C(C(C(O1)(CO)O)O)O)O
Isomeric SMILES:C1[C@H]([C@@H]([C@@H]([C@](O1)(CO)O)O)O)O

Technology Process of beta-D-tagatopyranose

There total 1 articles about beta-D-tagatopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1113-60-6
3-hydroxy-2-oxopropionic acid

: 95-43-2
D-threose

: 512-20-9
α-D-tagatopyranose

: 20197-42-6
tagatose (β-pyranose)

: 87-81-0,18875-34-8
D-tagatose

Guidance literature:: 3-hydroxy-2-oxopropionic acid; With magnesium(II) chloride hexahydrate; pyridoxal 5'-phosphate; transketolase from geobacillus stearothermophilus; thiamine diphosphate; In water; at 60 ℃; for 0.333333h; pH=7; Enzymatic reaction;

D-threose; With L-serin; sodium hydroxide; In water; at 60 ℃; for 96h; pH=7; Overall yield = 52 percent; Overall yield = 93 mg;
DOI:10.1002/cctc.201901756

Reference yield:

: 20197-42-6
tagatose (β-pyranose)

: 194991-50-9,53319-04-3
(2S,3S,4R,5S)-2-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol

: 71075-63-3
6-deoxy-D-glucitol

: 50-70-4
D-sorbitol

: 154-58-5,53319-04-3
1,5-anhydro-D-glucitol

Guidance literature:: Multi-step reaction with 3 steps

1.1: acetyl chloride / 96 h / 0 - 25 °C

2.1: 1,1,1,3,3,3-hexamethyl-disilazane / dichloromethane / 25 °C

3.1: bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane / chloroform-d1 / 15 h / 25 °C / Inert atmosphere; Glovebox

3.2: Dowex? / Inert atmosphere; Glovebox

With bis(pentafluorophenyl)borinic acid; acetyl chloride; 1,1,1,3,3,3-hexamethyl-disilazane; 1,1,3,3-tetramethyldisilazane; In chloroform-d1; dichloromethane;
DOI:10.1002/anie.201708109