5H-3,5a-Epoxynaphth[2,1-c]o

Base Information

• Chemical Name: 5H-3,5a-Epoxynaphth[2,1-c]o
• CAS No.: 1153-34-0
• Molecular Formula: C18H30 O2
• Molecular Weight: 278.435
• European Community (EC) Number: 701-522-8
• Nikkaji Number: J520.197G
• Mol file: 1153-34-0.mol

Synonyms:5H-3,5a-Epoxynaphth[2,1-c]o;1153-34-0;(1R,4S,9S,10R,13S)-5,5,9,13-tetramethyl-14,16-dioxatetracyclo[11.2.1.01,10.04,9]hexadecane;SCHEMBL1291882

Chemical Property of 5H-3,5a-Epoxynaphth[2,1-c]o

Chemical Property:

• PSA: 18.46000
• LogP: 4.52460
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 278.224580195
• Heavy Atom Count: 20
• Complexity: 431

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CCCC2(C1CCC34C2CCC(O3)(OC4)C)C)C
• Isomeric SMILES: C[C@]12CCCC([C@@H]1CC[C@]34[C@@H]2CC[C@](O3)(OC4)C)(C)C

Technology Process of 5H-3,5a-Epoxynaphth[2,1-c]o

There total 26 articles about 5H-3,5a-Epoxynaphth[2,1-c]o which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C18H30O2 (914799-48-7) → epiambraketal (1153-34-0,1153-35-1,57345-19-4,67010-56-4,67010-57-5,98677-12-4,98677-13-5)

Guidance literature:

With copper(II) sulfate; In dichloromethane; for 2h;

DOI:10.1016/0040-4039(94)88171-5

Reference yield: 90.0%

15,16-Dinorlabd-8(17)-en-13-on (10266-75-8,66971-94-6,72446-32-3) → ambracetal (1153-34-0,1153-35-1,57345-19-4,67010-56-4,67010-57-5,98677-12-4,98677-13-5)

Guidance literature:

With pyridine; trimethylamine-N-oxide; osmium(VIII) oxide; In tert-butyl alcohol; for 6h; Heating;

DOI:10.1016/S0040-4039(00)74880-5

Reference yield: 90.0%

C18H30O2 (3910-88-1,5938-13-6,54809-26-6,54809-27-7) → epi-8-ambracetal (1153-34-0,1153-35-1,57345-19-4,67010-56-4,67010-57-5,98677-12-4,98677-13-5)

Guidance literature:

With pyridinium p-toluenesulfonate; In dichloromethane; for 3h; Heating;

DOI:10.1016/S0040-4039(00)74880-5

upstream raw materials:

manool

C₁₈H₃₀O₂

4-((1S,4aS,8aS)-5,5,8a-trimethyl-2-methylene-decahydronaphthalen-1-yl)butan-2-one

sclareol