3-Imino-3H-phenothiazin-7-amine

Base Information

• Chemical Name: 3-Imino-3H-phenothiazin-7-amine
• CAS No.: 135-59-1
• Deprecated CAS: 494-61-1
• Molecular Formula: C12H10N3S
• Molecular Weight: 227.29
• Hs Code.: 2930909090
• European Community (EC) Number: 205-204-5
• UNII: 3865S9RNBC
• DSSTox Substance ID: DTXSID90275689,DTXSID40928850
• Nikkaji Number: J5.607C
• Wikidata: Q82005832
• ChEMBL ID: CHEMBL1852070
• Mol file: 135-59-1.mol

Synonyms:3-Imino-3H-phenothiazin-7-amine;135-59-1;7-iminophenothiazin-3-amine;3H-Phenothiazin-7-amine, 3-imino-;UNII-3865S9RNBC;3865S9RNBC;EINECS 205-204-5;AI3-63011;C12-H9-N3-S;SCHEMBL2609274;CHEMBL1852070;DTXSID40928850;DTXSID90275689;3-Imino-3H-phenothiazine-7-amine;3-Imino-3H-phenothiazin-7-ylamine #;3H-PHENOTHIAZINE, 7-AMINO-3-IMINO-;494-61-1

Chemical Property of 3-Imino-3H-phenothiazin-7-amine

Chemical Property:

• Vapor Pressure: 3.85E-07mmHg at 25°C
• Refractive Index: 1.791
• Boiling Point: 416.3 °C at 760 mmHg
• Flash Point: 205.6 °C
• PSA: 93.17000
• Density: 1.48 g/cm³
• LogP: 1.06140
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 227.05171847
• Heavy Atom Count: 16
• Complexity: 422

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Dyes -> Azine Dyes
• Canonical SMILES: C1=CC2=C(C=C1N)SC3=CC(=N)C=CC3=N2
• Uses: THIONIN is for general nuclear staining; for counting bacteria in milk; as antioxidant for linseed oil. Has been used as catalyst in condensation of 1,3-butadienyl ethyl ether with maleic anhydride.

Technology Process of 3-Imino-3H-phenothiazin-7-amine

There total 19 articles about 3-Imino-3H-phenothiazin-7-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,4-phenylenediamine (106-50-3) → thionine (135-59-1)

Guidance literature:

With sulfur; at 150 - 180 ℃; nachfolgend Oxydation;

Reference yield:

→ thionine (135-59-1)

Guidance literature:

With hydrogenchloride; iron(III) chloride;

Reference yield:

thionine → thionine (135-59-1)

Guidance literature:

With [D]-sodium hydroxide;

DOI:10.1016/j.dyepig.2010.07.014

upstream raw materials:

azure A

1,4-phenylenediamine

leucothionine

ammonia

Downstream raw materials:

1,4-cyclohexadiene-1,2-dicarboxylic anhydride

3,7-diamino-2,4,6,8-tetrachloro-phenothiazinylium; chloride

Refernces

• 1、 Margulis, L. A.,Khudyakov, I. V.,Klimchuk, E. S.,Kuz'min, V. A.. "KINETICS OF THE (PHOTO)OXIDATION OF THE THIONINE LEUCO BASE WITH URANYL NITRATE". . p. 7 - 11. Retrieved 1990.