3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt

Base Information

• Chemical Name: 3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt
• CAS No.: 4746-12-7
• Molecular Formula: C7H11Na2O10P
• Molecular Weight: 332.109541
• Mol file: 4746-12-7.mol

Synonyms:

Chemical Property of 3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt

Chemical Property:

• Melting Point: >150°C (dec.)
• PSA: 0.00000
• LogP: 0.00000
• Storage Temp.: Hygroscopic, -20°C Freezer, Under Inert Atmosphere
• Solubility.: Water (Slightly)

Purity/Quality:

95% ^*data from raw suppliers

3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: It stands at the beginning of the enzyme-catalyzed cascade that starts with this seven-carbon carbohydrate and ends with the aromatic amino acids phenylalanine, tyrosine, and tryptophan.

Technology Process of 3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt

There total 6 articles about 3-Deoxy-D-arabinoheptulosonic Acid 7-Phosphate Disodium Salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-1-((S)-3-Benzyloxymethyl-4,5-dihydro-isoxazol-5-yl)-ethane-1,2-diol (104048-51-3,104048-52-4) → 3-deoxy-threo-hexulose (4746-12-7,6196-57-2,84025-91-2)

Guidance literature:

With quinoline; hydrogen; Pd-BaSO₄; In methanol; water; for 2h;

DOI:10.1016/S0040-4020(01)91358-4

Reference yield:

(R)-1-((S)-3-Benzyloxymethyl-4,5-dihydro-isoxazol-5-yl)-ethane-1,2-diol (104048-51-3,104048-52-4) → 3-deoxy-erytro-hexulose (4746-12-7,6196-57-2,84025-91-2)

Guidance literature:

With quinoline; hydrogen; Pd-BaSO₄; In methanol; water; for 2h;

DOI:10.1016/S0040-4020(01)91358-4

Reference yield:

3-Benzyloxymethyl-5-vinyl-4,5-dihydro-isoxazole (104048-40-0) → 3-deoxy-threo-hexulose (4746-12-7,6196-57-2,84025-91-2)

Guidance literature:

Multi-step reaction with 2 steps

1: OsO₄, H₂O₂ / acetone; H₂O / 0 °C

2: H₂, quinoline / Pd/BaSO₄ / methanol; H₂O / 2 h

With quinoline; osmium(VIII) oxide; hydrogen; dihydrogen peroxide; Pd-BaSO₄; In methanol; water; acetone;

DOI:10.1016/S0040-4020(01)91358-4

upstream raw materials:

D-lyxo-3-deoxy-hexose

(S)-1-((S)-3-Benzyloxymethyl-4,5-dihydro-isoxazol-5-yl)-ethane-1,2-diol

3-Benzyloxymethyl-5-vinyl-4,5-dihydro-isoxazole

(R)-1-((S)-3-Benzyloxymethyl-4,5-dihydro-isoxazol-5-yl)-ethane-1,2-diol

Refernces