Bromomethyl radical

Base Information

• Chemical Name: Bromomethyl radical
• CAS No.: 16519-97-4
• Molecular Formula: CH2 Br
• Molecular Weight: 93.9309
• Mol file: 16519-97-4.mol

Synonyms:Bromomethyl;Bromomethyl radical

Chemical Property of Bromomethyl radical

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.88810

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bromomethyl radical

There total 20 articles about Bromomethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

CH3(1+)*CH2Br + acetonitrile (75-05-8,26809-02-9) → methyl bromide (74-83-9) + bromomethyl radical (16519-97-4) + C3H5N(1+) (98587-57-6) + dimethyl-nitrilium cation (21963-22-4)

Guidance literature:

Quantum yield; FT-ICR investigations;

Reference yield:

α-(BrCH2)nickel(III)(1,4,8,11-tetraazacyclotetradecane)(H2O)(2+) → R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+) (890854-65-6,52610-79-4,46365-93-9,186321-89-1,186358-88-3,186321-88-0,104319-03-1) + bromomethyl radical (16519-97-4)

Guidance literature:

With perchloric acid; sodium perchlorate; In water; Irradiation (UV/VIS); laser flash photolysis at 25°C; gas chromy. detn.; Kinetics;

DOI:10.1021/ja00020a020

Reference yield:

β-(BrCH2)nickel(III)(1,4,8,11-tetraazacyclotetradecane)(H2O)(2+) → R,R,S,S-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+) (890854-65-6,186358-88-3,186321-89-1,46365-93-9,186321-88-0,52610-79-4,104319-03-1) + bromomethyl radical (16519-97-4)

Guidance literature:

With perchloric acid; In water; Irradiation (UV/VIS); laser flash photolysis at 25°C; gas chromy. detn.; Kinetics;

DOI:10.1021/ja00020a020

upstream raw materials:

methyl bromide

cyclopentadienylidene anion radical

acetonitrile

Bromomethane

Downstream raw materials:

chlorobromomethane

1,1-dibromomethane

methyl bromide