Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans-

Base Information

• Chemical Name: Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans-
• CAS No.: 6772-77-6
• Molecular Formula: C13H10 Cl N
• Molecular Weight: 215.682
• NSC Number: 98858,4109,3917
• Nikkaji Number: J542.693F
• Mol file: 6772-77-6.mol

Synonyms:6772-77-6;Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans-;2-[2-(2-chlorophenyl)ethenyl]pyridine;5350-12-9;NSC3917;SCHEMBL4710047;NSC4109;NSC-3917;NSC-4109;NSC98858;NSC-98858;2-[(E)-2-(2-Chlorophenyl)vinyl]pyridine;Pyridine, 2-(2-(chlorophenyl)vinyl) trans-;Pyridine,2-[2-(2-chlorophenyl)ethenyl]-(E);2739-76-6

Chemical Property of Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans-

Chemical Property:

• Vapor Pressure: 0.000243mmHg at 25°C
• Melting Point: 78 - 79 °C (hexane)
• Boiling Point: 334.8°C at 760 mmHg
• Flash Point: 186.5°C
• PSA: 12.89000
• Density: 1.212g/cm³
• LogP: 3.90540
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 215.0501770
• Heavy Atom Count: 15
• Complexity: 215

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C=CC2=CC=CC=N2)Cl
• Isomeric SMILES: C1=CC=C(C(=C1)/C=C/C2=CC=CC=N2)Cl

Technology Process of Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans-

There total 3 articles about Pyridine, 2-(2-(chlorophenyl)vinyl)-, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

α-picoline (109-06-8) + 2-chloro-benzaldehyde (89-98-5) → (E)-2-[2-(chlorophenyl)vinyl]pyridine (6772-77-6,5350-12-9)

Guidance literature:

With acetic anhydride; for 20h; Reflux; Inert atmosphere;

DOI:10.1016/j.tet.2011.03.023

Reference yield:

→ (E)-2-[2-(chlorophenyl)vinyl]pyridine (6772-77-6,5350-12-9)

Guidance literature:

With water; copper(l) chloride; Behandeln einer Loesung des Reaktionsprodukts in wss.Salpetersaeure mit wss.Ammoniak_.;

DOI:10.1039/jr9460000673

Reference yield:

→ (E)-2-[2-(chlorophenyl)vinyl]pyridine (6772-77-6,5350-12-9)

Guidance literature:

DOI:10.1021/jo01345a063

upstream raw materials:

α-picoline

2-chloro-benzaldehyde

Downstream raw materials:

Dehydrobenzochinoliziniumchlorid

cis-2'-Chlor-2-stilbazol

Refernces

• 1、 Arai, Sadao,Arai, Hitoshi,Tabuchi, Kunihisa,Yamagishi, Takamichi,Hida, Mitsuhiko. "Synthesis and Reactions of Methylbenzoquinolizinium Salts". . p. 215 - 220. Retrieved 2007/10/02.