9-anthryloxirane

Base Information

• Chemical Name: 9-anthryloxirane
• CAS No.: 61695-73-6
• Molecular Formula: C16H12 O
• Molecular Weight: 220.271
• Hs Code.: 2910900090
• Mol file: 61695-73-6.mol

Synonyms:Oxirane,9-anthracenyl- (9CI); 9-Anthryloxirane; 9-Oxiranylanthracene

Chemical Property of 9-anthryloxirane

Chemical Property:

• Vapor Pressure: 6.74E-07mmHg at 25°C
• Melting Point: 68-69 °C(Solv: ethanol (64-17-5))
• Boiling Point: 420.7°C at 760 mmHg
• Flash Point: 198.3°C
• PSA: 12.53000
• Density: 1.246g/cm³
• LogP: 4.06430

Purity/Quality:

97% ^*data from raw suppliers

9-ANTHRYLOXIRANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-anthryloxirane

There total 5 articles about 9-anthryloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

trimethylsulphonium iodide (2181-42-2) + 9-anthracene aldehyde (642-31-9) → 1-(9-anthryl)-ethylene oxide (61695-73-6)

Guidance literature:

With water; potassium hydroxide; In acetonitrile; at 60 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.polymer.2015.10.043

Reference yield:

9-vinylanthracene (2444-68-0) → 1-(9-anthryl)-ethylene oxide (61695-73-6) + 9-anthracene aldehyde (642-31-9)

Guidance literature:

With C₂₄H₂₃MnN₅O₅S₂; oxygen; isovaleraldehyde; In acetonitrile; at 30 ℃; for 4h;

DOI:10.1039/c4dt02079k

Reference yield:

9-vinylanthracene (2444-68-0) → 1-(9-anthryl)-ethylene oxide (61695-73-6)

Guidance literature:

With tert.-butylhydroperoxide; 2C₂₁H₁₃N₃O₆^(2-)*3Mn⁽²⁺⁾*Co⁽²⁺⁾*HO^(1-)*16H₂O; In neat (no solvent); at 50 ℃; for 4h; Green chemistry;

DOI:10.1021/ic502772k

upstream raw materials:

9-vinylanthracene

trimethylsulphonium iodide

9-anthracene aldehyde

Downstream raw materials:

2-amino-2-(anthracen-9-yl)ethanol

4-(anthracen-9-yl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole

Refernces

• 1、 Kumar, Gulshan,Hussain, Firasat,Gupta, Rajeev. "Copper based coordination polymers based on metalloligands: Utilization as heterogeneous oxidation catalysts". . p. 16985 - 16994. Retrieved 2019/01/03.
• 2、 Yadav, Sunil,Kumar, Sushil,Gupta, Rajeev. "Manganese Complexes of Pyrrole- and Indolecarboxamide Ligands: Synthesis, Structure, Electrochemistry, and Applications in Oxidative and Lewis-Acid-Assisted Catalysis". . p. 5534 - 5544. Retrieved 2015/12/01.