(7S)-7β-(3-Amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyloxy)-9α-methyl-7,8,9,10-tetrahydro-6,9,11-trihydroxynaphthacene-5,12-dione

Base Information

Chemical Name:(7S)-7β-(3-Amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyloxy)-9α-methyl-7,8,9,10-tetrahydro-6,9,11-trihydroxynaphthacene-5,12-dione
CAS No.:81844-87-3
Molecular Formula:C₂₅H₂₇NO₈
Molecular Weight:469.491
Hs Code.:
Mol file:81844-87-3.mol

Synonyms:

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Chemical Property of (7S)-7β-(3-Amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyloxy)-9α-methyl-7,8,9,10-tetrahydro-6,9,11-trihydroxynaphthacene-5,12-dione

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Technology Process of (7S)-7β-(3-Amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyloxy)-9α-methyl-7,8,9,10-tetrahydro-6,9,11-trihydroxynaphthacene-5,12-dione

There total 8 articles about (7S)-7β-(3-Amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyloxy)-9α-methyl-7,8,9,10-tetrahydro-6,9,11-trihydroxynaphthacene-5,12-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78499-72-6,81844-81-7
(1S)-cis-1-[(2,3,6-trideoxy-3-trifluoroacetamido-α-L-lyxohexopyranosyl)oxy]-1,2,3,4,6,11-hexahydro-3,5,12-trihydroxy-3-methyl-6,11-dioxonaphthacene

: 81844-87-3,81844-88-4
(7S,9S)-7-<(3'-amino-2',3',6'-trideoxy-α-L-lyxohexopyranosyl)oxy>-7,8,9,10-tetrahydro-6,9,11-trihydroxy-9-methyl-5,12-naphthacenedione

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; for 1h;
DOI:10.1021/jm00171a010

Reference yield:

: 78499-72-6,81844-81-7
2,2,2-Trifluoro-N-[(2S,3R,4S,6R)-3-hydroxy-2-methyl-6-((1S,3S)-3,5,12-trihydroxy-3-methyl-6,11-dioxo-1,2,3,4,6,11-hexahydro-naphthacen-1-yloxy)-tetrahydro-pyran-4-yl]-acetamide

: 81844-87-3,81844-88-4
(7S,9S)-7-<(3'-amino-2',3',6'-trideoxy-α-L-arabinohexapyranosyl)oxy>-7,8,9,10-tetrahydro-6,9,11-trihydroxy-9-methyl-5,12-naphthacenedione

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; water; for 1h;
DOI:10.1021/jm00171a010

Reference yield:

: 128572-89-4
4-Nitro-benzoic acid (2S,3R,4S)-6-chloro-2-methyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester

: 81844-87-3,81844-88-4
(7S,9S)-7-<(3'-amino-2',3',6'-trideoxy-α-L-arabinohexapyranosyl)oxy>-7,8,9,10-tetrahydro-6,9,11-trihydroxy-9-methyl-5,12-naphthacenedione

Guidance literature:: Multi-step reaction with 3 steps

1: silver trifluoromethanesulfonate / tetrahydrofuran; diethyl ether / 3.5 h / -5 °C

2: 0.1 M aq. NaOH / CH₂Cl₂; methanol / 0.5 h / 0 °C

3: 0.1 M aq. NaOH / tetrahydrofuran; H₂O / 1 h

With sodium hydroxide; silver trifluoromethanesulfonate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water;
DOI:10.1021/jm00171a010