(E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide

Base Information

Chemical Name:(E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide
CAS No.:112930-69-5
Molecular Formula:C₁₇H₁₅NOS
Molecular Weight:281.378
Hs Code.:
Wikidata:Q76389907

Synonyms:BRN 4461572;Propanamide, 3-dibenzo(b,e)thiepin-11(6H)-ylidene-, (E)-;(E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide;112930-69-5;AKOS005066338;LS-119133

Suppliers and Price of (E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide

Chemical Property:

Vapor Pressure:6.81E-11mmHg at 25°C
Boiling Point:519.5°Cat760mmHg
Flash Point:268°C
Density:1.291g/cm³
XLogP3:3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:281.08743528
Heavy Atom Count:20
Complexity:393

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C2=CC=CC=C2C(=CCC(=O)N)C3=CC=CC=C3S1
Isomeric SMILES:C1C2=CC=CC=C2/C(=C\CC(=O)N)/C3=CC=CC=C3S1

Technology Process of (E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide

There total 6 articles about (E)-3-(6,11-Dihydrodibenzo(b,e)thiepin-11-ylidene)propionamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 112930-66-2
3-(6,11-dihydrodibenzothiepin-11-ylidene)propionyl chloride

: 112930-69-5
3-(6,11-dihydrodibenzothiepin-11-ylidene)propionamide

Guidance literature:: With ammonia; In chloroform; 1) 10 deg C, 1 h; 2) room temp., 3 h;

Reference yield:

: 1531-77-7
dibenzo[b,e]thiepin-11(6H)-one

: 112930-69-5
3-(6,11-dihydrodibenzothiepin-11-ylidene)propionamide

Guidance literature:: Multi-step reaction with 6 steps

1: 1) Mg / in THF

2: 94 percent / HBr / acetic acid / 1 h / 15 °C

3: 80 percent / tetrahydrofuran; ethanol; H₂O / 1.5 h / Ambient temperature

4: aq. KOH / ethanol / 3.5 h / Heating

5: 97 percent / SOCl₂ / benzene / 3 h / Heating

6: 64 percent / NH₃ / CHCl₃ / 1) 10 deg C, 1 h; 2) room temp., 3 h

With potassium hydroxide; thionyl chloride; ammonia; hydrogen bromide; magnesium; In tetrahydrofuran; ethanol; chloroform; water; acetic acid; benzene;

Reference yield:

: 112930-52-6
6,11-Dihydro-11-vinyldibenzothiepin-11-ol

: 112930-69-5
3-(6,11-dihydrodibenzothiepin-11-ylidene)propionamide

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / HBr / acetic acid / 1 h / 15 °C

2: 80 percent / tetrahydrofuran; ethanol; H₂O / 1.5 h / Ambient temperature

3: aq. KOH / ethanol / 3.5 h / Heating

4: 97 percent / SOCl₂ / benzene / 3 h / Heating

5: 64 percent / NH₃ / CHCl₃ / 1) 10 deg C, 1 h; 2) room temp., 3 h

With potassium hydroxide; thionyl chloride; ammonia; hydrogen bromide; In tetrahydrofuran; ethanol; chloroform; water; acetic acid; benzene;