2-Dodec-11-enyloxirane

Base Information

• Chemical Name: 2-Dodec-11-enyloxirane
• CAS No.: 69227-94-7
• Molecular Formula: C14H26 O
• Molecular Weight: 210.36
• European Community (EC) Number: 273-929-4
• DSSTox Substance ID: DTXSID90988949
• Nikkaji Number: J317.958C
• Mol file: 69227-94-7.mol

Synonyms:2-Dodec-11-enyloxirane;EINECS 273-929-4;69227-94-7;2-(11-Dodecenyl)oxirane;SCHEMBL5398476;DTXSID90988949;2-(DODEC-11-EN-1-YL)OXIRANE

Chemical Property of 2-Dodec-11-enyloxirane

Chemical Property:

• Vapor Pressure: 0.0275mmHg at 25°C
• Boiling Point: 254.5°C at 760 mmHg
• Flash Point: 95.5°C
• PSA: 12.53000
• Density: 0.869g/cm³
• LogP: 4.47220
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 210.198365449
• Heavy Atom Count: 15
• Complexity: 153

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCCCCCCCC1CO1

Technology Process of 2-Dodec-11-enyloxirane

There total 1 articles about 2-Dodec-11-enyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetradeca-1,13-diene (21964-49-8) → 1,2-Epoxy-11-tetradecene (69227-94-7)

Guidance literature:

With oxygen; isobutyraldehyde; NPV₆Mo₆; In 1,2-dichloro-ethane; at 25 ℃; for 4h; under 760 Torr; Yield given;

DOI:10.1021/jo00075a043

Reference yield:

iodobenzene (591-50-4) + 1,2-Epoxy-11-tetradecene (69227-94-7) → (Z)-14-Phenyl-tetradec-2-en-1-ol (130700-12-8) + (E)-14-Phenyl-tetradec-2-en-1-ol (130700-11-7)

Guidance literature:

With lithium formate; tetrabutyl-ammonium chloride; N-ethyl-N,N-diisopropylamine; lithium chloride; palladium diacetate; In N,N-dimethyl-formamide; at 50 ℃; for 48h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00313a006

upstream raw materials:

tetradeca-1,13-diene

Downstream raw materials:

(Z)-14-Phenyl-tetradec-2-en-1-ol

(E)-14-Phenyl-tetradec-2-en-1-ol

Refernces