tridodecylborane

Base Information

• Chemical Name: tridodecylborane
• CAS No.: 14245-38-6
• Molecular Formula: C₃₆H₇₅B
• Molecular Weight: 518.803
• Mol file: 14245-38-6.mol

Synonyms:Borine,tridodecyl- (6CI); NSC 524969; Tridodecylborane

Chemical Property of tridodecylborane

Chemical Property:

• Vapor Pressure: 1E-12mmHg at 25°C
• Boiling Point: 577.3°Cat760mmHg
• Flash Point: 302.9°C
• Density: 0.804g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tridodecylborane

There total 3 articles about tridodecylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Tridodecyl-boran (14245-38-6)

Guidance literature:

With boron trifluoride diethyl etherate;

DOI:10.1246/bcsj.36.868

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) → Tridodecyl-boran (14245-38-6) + C18H29BO2

Guidance literature:

With N,N-dimethyl acetamide; In dichloromethane; for 3h; Mechanism; Ambient temperature; other olefins, N,N-dimethylacetamide absence;

DOI:10.1021/jo960386p

Reference yield:

→ Tridodecyl-boran (14245-38-6)

Guidance literature:

1-Dodecen, 1. BH3, THF, 2. Anisol, 3. DMSO, Δ;

DOI:10.1246/bcsj.52.271

upstream raw materials:

1-dodecene

Refernces

• 1、 Garrett, Christine E.,Fu, Gregory C.. "Hydroboration of olefins with catecholborane at room temperature in the presence of N,N-dimethylacetamide". . p. 3224 - 3225. Retrieved 2007/10/03.