3(15),7(14),10-Bisabolatriene

Base Information

• Chemical Name: 3(15),7(14),10-Bisabolatriene
• CAS No.: 6009-90-1
• Molecular Formula: C₁₅H₂₄
• Molecular Weight: 204.356
• Mol file: 6009-90-1.mol

Synonyms:1-Methylene-4-(5-methyl-1-methylene-hex-4-enyl)-cyclohexane;Isobisabolen;Isobisabolene;

Chemical Property of 3(15),7(14),10-Bisabolatriene

Chemical Property:

• Boiling Point: 104 - 105 °C (8 mmHg)
• PSA: 0.00000
• LogP: 5.03540

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3(15),7(14),10-Bisabolatriene

There total 6 articles about 3(15),7(14),10-Bisabolatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7-methyl-1,6-octadiene-3-one (24903-94-4) → iso-bisabolene (6009-90-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / aluminium trichloride / CH₂Cl₂ / 6 h / 30 °C

2: 2.) HCl / 1.) Et₂O, 35 deg C, 3 h, 2.) methanol, 65 deg C , 3 h

With hydrogenchloride; aluminium trichloride; In dichloromethane;

DOI:10.1016/S0040-4020(01)88587-2

Reference yield:

7-(5-Methyl-1-methylene-hex-4-enyl)-1,3-dioxa-spiro[3.5]nonane → iso-bisabolene (6009-90-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. HCl / acetone

2: dimethylsulfoxide

With hydrogenchloride; In dimethyl sulfoxide; acetone;

Reference yield:

(trimethylsilyl)methylmagnesium chloride (13170-43-9) + 5-Methyl-1-(4-trimethylsilanylmethyl-cyclohex-3-enyl)-hex-4-en-1-one (82096-08-0) → iso-bisabolene (6009-90-1)

Guidance literature:

With hydrogenchloride; Multistep reaction; 1.) Et₂O, reflux 3 h; 2.) MeOH, rt, 15 h;

DOI:10.1016/S0040-4039(00)86886-0

upstream raw materials:

4-(5-Methyl-hex-4-enoyl)-cyclohexanone

methyl-triphenylphosphonium iodide

dimethyl sulfoxide

6-Methyl-2-(4-oxo-cyclohexyl)-1.5-heptadien