N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine

Base Information

• Chemical Name: N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine
• CAS No.: 4608-47-3
• Molecular Formula: C10H17NO
• Molecular Weight: 167.2481
• DSSTox Substance ID: DTXSID20410622
• Mol file: 4608-47-3.mol

Synonyms:4608-47-3;DTXSID20410622;N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine;4,6,6-trimethylbicyclo[3.1.1]heptan-2-one oxime

Chemical Property of N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine

Chemical Property:

• Vapor Pressure: 0.00668mmHg at 25°C
• Melting Point: 68-69 °C
• Boiling Point: 250.9°Cat760mmHg
• Flash Point: 142.5°C
• PSA: 32.59000
• Density: 1.18g/cm³
• LogP: 2.51870
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 167.131014166
• Heavy Atom Count: 12
• Complexity: 232

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CC(=NO)C2CC1C2(C)C

Technology Process of N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine

There total 7 articles about N-(4,6,6-Trimethylbicyclo[3.1.1]heptan-2-ylidene)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(-)-kaurene (469-85-2,469-86-3,562-28-7,10178-84-4,13850-19-6,20070-61-5,87759-99-7) → C20H31Br (4608-45-1,4608-47-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 220 mg / iodine / benzene / 12 h / Heating

2: bromosuccinimide

With N-Bromosuccinimide; iodine; In benzene;

DOI:10.1007/BF00634741

Reference yield:

16-α-Chlorophyllocladan → 17-Brom-phylloclad-15-en (4608-47-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Al₂O₃

2: NBS, (PhCO)2O₂ / Irradiation

With aluminum oxide; N-Bromosuccinimide; dibenzoyl peroxide;

DOI:10.1039/jr9650006212

Reference yield:

phyllocladene (469-86-3) → 17-Brom-phylloclad-15-en (4608-47-3)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; Irradiation;

DOI:10.1039/jr9650006212

upstream raw materials:

isophyllocladene

phyllocladene

16,17-Dibrom-phyllocladan

Isokauren

Downstream raw materials:

Phylloclad-15-en-17-ol