N-(3-Methyl-2-butenyl)phthalimide

Base Information

• Chemical Name: N-(3-Methyl-2-butenyl)phthalimide
• CAS No.: 15936-45-5
• Molecular Formula: C13H13 N O2
• Molecular Weight: 215.252
• Hs Code.: 2925190090
• European Community (EC) Number: 633-917-5
• NSC Number: 84144
• DSSTox Substance ID: DTXSID30166643
• Nikkaji Number: J50.522F
• Mol file: 15936-45-5.mol

Synonyms:15936-45-5;N-(3-Methyl-2-butenyl)phthalimide;Phthalimide, N-(3-methyl-2-butenyl)-;2-(3-Methylbut-2-en-1-yl)isoindoline-1,3-dione;2-(3-methylbut-2-enyl)isoindole-1,3-dione;NSC 84144;BRN 0165108;1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-2-butenyl)-;5-21-10-00284 (Beilstein Handbook Reference);1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-2-buten-1-yl)-;N-[3-Methyl-2-butenyl]phthalimide;NSC84144;NCIOpen2_004630;3-Methyl-2-butenylphthalimide;SCHEMBL4017572;3-methyl-1-phthalimido-2-butene;DTXSID30166643;2-(3-methylbut-2-en-1-yl)-2,3-dihydro-1H-isoindole-1,3-dione;NSC-84144;WLN: T56 BVNVJ C2UY1&1;AKOS022179299;SB65559;LS-109494;CS-0434655;FT-0688516;1H-Isoindole-1, 2-(3-methyl-2-butenyl)-;EN300-171284;N-(3-METHYL-2-BUTEN-1-YL)PHTHALIMIDE;2-(3-methylbut-2-en-1-yl)-1H-isoindole-1,3-dione;2-(3-Methyl-2-butenyl)-1H-isoindole-1,3(2H)-dione #

Chemical Property of N-(3-Methyl-2-butenyl)phthalimide

Chemical Property:

• Vapor Pressure: 0.000196mmHg at 25°C
• Melting Point: 97-99 °C
• Boiling Point: 327.9°Cat760mmHg
• PKA: -2.12±0.20(Predicted)
• Flash Point: 139°C
• PSA: 37.38000
• Density: 1.175g/cm³
• LogP: 2.18670
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 215.094628657
• Heavy Atom Count: 16
• Complexity: 318

Purity/Quality:

99% ^*data from raw suppliers

2-(3-methylbut-2-en-1-yl)-2,3-dihydro-1H-isoindole-1,3-dione ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CCN1C(=O)C2=CC=CC=C2C1=O)C

Technology Process of N-(3-Methyl-2-butenyl)phthalimide

There total 15 articles about N-(3-Methyl-2-butenyl)phthalimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

potassium phtalimide (1074-82-4) + prenyl bromide (870-63-3) → N-prenylphthalimide (15936-45-5)

Guidance literature:

In N,N-dimethyl-formamide; at 120 - 160 ℃; for 19h;

DOI:10.1021/jm8011933

Reference yield: 93.0%

phthalimide (136918-14-4,85-41-6) + 1-iodo-3-methyl-but-2-ene (41004-19-7) → N-prenylphthalimide (15936-45-5)

Guidance literature:

With potassium fluoride on basic alumina; In 2-methyltetrahydrofuran; at 90 ℃; for 4h; chemoselective reaction; Inert atmosphere;

DOI:10.1039/c0gc00113a

Reference yield: 76.0%

potassium phtalimide (1074-82-4) → N-prenylphthalimide (15936-45-5)

Guidance literature:

In N,N-dimethyl-formamide; at 60 ℃; Inert atmosphere;

upstream raw materials:

1,3-dichloro-3-methylbutane

potassium phtalimide

4-chloro-2-methyl-2-butanol

prenyl bromide

Downstream raw materials:

3,3-dimethylallylamine

(3-methyl-2-butenyl)amine hydrochloride

3-methyl-3-phenylselanyl-butylamine

N-cyano-N-(3-methyl-3-(phenylselanyl)butyl)benzamide