Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside

Base Information

Chemical Name:Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside
CAS No.:139978-92-0
Molecular Formula:C₁₄H₂₆O₁₁
Molecular Weight:370.354
Hs Code.:
DSSTox Substance ID:DTXSID50930681
Wikidata:Q82906097
Mol file:139978-92-0.mol

Synonyms:MDMHG;methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside

Suppliers and Price of Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside

Chemical Property:

Vapor Pressure:1.25E-19mmHg at 25°C
Boiling Point:649.7°Cat760mmHg
Flash Point:346.7°C
PSA：178.53000
Density:1.57g/cm³
LogP:-4.35300
XLogP3:-4.4
Hydrogen Bond Donor Count:7
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:6
Exact Mass:370.14751164
Heavy Atom Count:25
Complexity:410

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C(C(C(C(O1)CO)OC2C(C(C(C(O2)CCO)O)O)O)O)O
Isomeric SMILES:CO[C@H]1[C@@H]([C@H]([C@H]([C@H](O1)CO)O[C@@H]2[C@H]([C@H]([C@@H]([C@H](O2)CCO)O)O)O)O)O

Technology Process of Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside

There total 3 articles about Methyl 4-O-(6-deoxy-manno-heptopyranosyl)galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 51842-16-1
methyl 2,3,6-tri-O-benzyl-β-D-galactopyranoside

: 139978-92-0
methyl 4-O-(6-deoxy-α-D-manno-heptopyranosyl)-β-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / N-iodosuccinimide, molecular sieves 4 Angstroem / triflic acid / 1,2-dichloro-ethane; diethyl ether / 0.08 h / Ambient temperature

2: 1) sodium methoxide, 2) hydrogen / 2) Pd/C (10percent) / 1) methanol, 18h, room temperature, 2) 2-propanol, water, acetic acid, 24h, room temperature

With N-iodo-succinimide; 4 A molecular sieve; hydrogen; sodium methylate; palladium on activated charcoal; trifluorormethanesulfonic acid; In diethyl ether; 1,2-dichloro-ethane;
DOI:10.1016/0008-6215(92)84105-2

Reference yield:

: 139978-89-5,139978-95-3
ethyl 2,3,4,7-tetra-O-benzoyl-6-deoxy-1-thio-α,β-D-manno-heptopyranoside

: 139978-92-0
methyl 4-O-(6-deoxy-α-D-manno-heptopyranosyl)-β-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / N-iodosuccinimide, molecular sieves 4 Angstroem / triflic acid / 1,2-dichloro-ethane; diethyl ether / 0.08 h / Ambient temperature

2: 1) sodium methoxide, 2) hydrogen / 2) Pd/C (10percent) / 1) methanol, 18h, room temperature, 2) 2-propanol, water, acetic acid, 24h, room temperature

With N-iodo-succinimide; 4 A molecular sieve; hydrogen; sodium methylate; palladium on activated charcoal; trifluorormethanesulfonic acid; In diethyl ether; 1,2-dichloro-ethane;
DOI:10.1016/0008-6215(92)84105-2

Reference yield:

: 139978-91-9
methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,7-O-benzoyl-6-deoxy-α-D-manno-heptopyranosyl)-β-D-galactopyranoside

: 139978-92-0
methyl 4-O-(6-deoxy-α-D-manno-heptopyranosyl)-β-galactopyranoside

Guidance literature:: With hydrogen; sodium methylate; palladium on activated charcoal; Yield given. Multistep reaction; 1) methanol, 18h, room temperature, 2) 2-propanol, water, acetic acid, 24h, room temperature;
DOI:10.1016/0008-6215(92)84105-2