2,2'-Bipyridine-5,5'-dicarbonitrile

Base Information

Chemical Name:2,2'-Bipyridine-5,5'-dicarbonitrile
CAS No.:1802-29-5
Molecular Formula:C12H6N4
Molecular Weight:206.2
Hs Code.:2933399090
European Community (EC) Number:801-744-6
DSSTox Substance ID:DTXSID90453445
Nikkaji Number:J1.065.579J
Wikidata:Q82274588
Mol file:1802-29-5.mol

Synonyms:1802-29-5;[2,2'-Bipyridine]-5,5'-dicarbonitrile;2,2'-BIPYRIDINE-5,5'-DICARBONITRILE;6-(5-cyanopyridin-2-yl)pyridine-3-carbonitrile;5,5'-dicyano-2,2'-bipyridine;(2,2'-bipyridine)-5,5'-dicarbonitrile;YSWG089;SCHEMBL995794;HFGASMNBMUOCGQ-UHFFFAOYSA-;DTXSID90453445;MFCD11855995;AKOS015854257;2,2/'-Bipyridine-5,5/'-dicarbonitrile;AS-63079;CS-0110286;D82433;A881142;J-400678;2,2 inverted exclamation mark -Bipyridine-5,5 inverted exclamation mark -dicarbonitrile;InChI=1/C12H6N4/c13-5-9-1-3-11(15-7-9)12-4-2-10(6-14)8-16-12/h1-4,7-8H

Suppliers and Price of 2,2'-Bipyridine-5,5'-dicarbonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
[2,2''-bipyridine]-5,5''-dicarbonitrile
50mg
$ 130.00

Matrix Scientific
[2,2'-Bipyridine]-5,5'-dicarbonitrile 95+%
1g
$ 1647.00

Matrix Scientific
[2,2'-Bipyridine]-5,5'-dicarbonitrile 95+%
250mg
$ 742.00

Crysdot
[2,2'-Bipyridine]-5,5'-dicarbonitrile 95+%
1g
$ 470.00

Chemenu
[2,2''-Bipyridine]-5,5''-dicarbonitrile 95%
1g
$ 445.00

American Custom Chemicals Corporation
[2,2'-BIPYRIDINE]-5,5'-DICARBONITRILE 95.00%
5MG
$ 499.52

Ambeed
[2,2'-Bipyridine]-5,5'-dicarbonitrile 97%
1g
$ 299.00

Ambeed
[2,2'-Bipyridine]-5,5'-dicarbonitrile 97%
250mg
$ 200.00

Ambeed
[2,2'-Bipyridine]-5,5'-dicarbonitrile 97%
100mg
$ 200.00

Alichem
[2,2'-Bipyridine]-5,5'-dicarbonitrile
25g
$ 3366.33

Total 23 raw suppliers

Chemical Property of 2,2'-Bipyridine-5,5'-dicarbonitrile

Chemical Property:

Melting Point:272-273 °C
Boiling Point:414.6±45.0 °C(Predicted)
PKA:0.12±0.32(Predicted)
PSA：73.36000
Density:1.32±0.1 g/cm3(Predicted)
LogP:1.88696
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:206.059246208
Heavy Atom Count:16
Complexity:299

Purity/Quality:

97% ^*data from raw suppliers

[2,2''-bipyridine]-5,5''-dicarbonitrile ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=NC=C1C#N)C2=NC=C(C=C2)C#N
General Description 2,2’-Bipyridine-5,5’-dicarbonitrile is a versatile ambidentate ligand capable of functioning as a bi-, tri-, or tetradentate chelator in coordination chemistry, forming discrete complexes or polymeric structures with metals like silver, depending on the anion and crystallization conditions. Its electron-withdrawing cyano groups enhance the electrochemical properties of metal complexes, enabling multicolor electrochromism in ruthenium(II) trisbipyridine systems. Additionally, it serves as a precursor for synthesizing donor-functionalized bipyridines and can be incorporated into porous organic polymers or covalent triazine frameworks for applications in catalysis and temperature sensing, owing to its stable nitrogen-metal interactions and tunable electronic properties.

Technology Process of 2,2'-Bipyridine-5,5'-dicarbonitrile

There total 9 articles about 2,2'-Bipyridine-5,5'-dicarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 139585-70-9
2-bromo-5-cyanopyridine

: 1802-29-5
2,2’-bipyridine-5,5’-dicarbonitrile

Guidance literature:: 2-bromo-5-cyanopyridine; With nickel(II) chloride hexahydrate; lithium chloride; zinc; In N,N-dimethyl-formamide; at 40 ℃;

With iodine; acetic acid; In N,N-dimethyl-formamide; at 50 ℃; for 0.5h;

With hydrogenchloride; In water; N,N-dimethyl-formamide; at 0 ℃; for 0.5h;
DOI:10.1016/j.jcat.2019.01.030

Reference yield: 86.0%

: 4444-36-4
2,2'-bipyridine-5,5'-bis(carboxamide)

: 1802-29-5
2,2’-bipyridine-5,5’-dicarbonitrile

Guidance literature:: With trichlorophosphate; for 61h; ultrasonication;
DOI:10.1016/0022-328X(88)89021-1

Reference yield: 67.0%

: 15862-18-7
5,5'-dibromo-2,2'-dipyridyl

: 143-33-9,25596-52-5
sodium cyanide

: 1802-29-5
2,2’-bipyridine-5,5’-dicarbonitrile

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; 1,5-bis-(diphenylphosphino)pentane; lead acetate; In 1,3,5-trimethyl-benzene; for 16h; Heating;
DOI:10.1055/s-2005-872113