4-n-Tetradecyloxybenzoic acid

Base Information

• Chemical Name: 4-n-Tetradecyloxybenzoic acid
• CAS No.: 15872-46-5
• Molecular Formula: C21H34 O3
• Molecular Weight: 334.499
• Hs Code.: 2918990090
• Mol file: 15872-46-5.mol

Synonyms:Benzoicacid, p-(tetradecyloxy)- (8CI); 4-(Tetradecyloxy)benzoic acid; NSC 151187; RMI13640; p-(Tetradecyloxy)benzoic acid; p-(n-Tetradecyloxy)benzoic acid

Chemical Property of 4-n-Tetradecyloxybenzoic acid

Chemical Property:

• Vapor Pressure: 3.96E-09mmHg at 25°C
• Boiling Point: 456.6°Cat760mmHg
• Flash Point: 149.3°C
• PSA: 46.53000
• Density: 0.982g/cm³
• LogP: 6.46470

Purity/Quality:

99% ^*data from raw suppliers

4-(TETRADECYLOXY)BENZOIC ACID Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-n-Tetradecyloxybenzoic acid

There total 25 articles about 4-n-Tetradecyloxybenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl 4-tetradecyloxybenzoate (40654-33-9) → 4-(tetradecyloxy)benzoic acid (15872-46-5)

Guidance literature:

With sodium hydroxide; In methanol; for 4h; Heating;

DOI:10.1016/j.ejmech.2005.03.027

Reference yield: 92.0%

1-Bromotetradecane (112-71-0) + 4-hydroxy-benzoic acid (99-96-7) → 4-(tetradecyloxy)benzoic acid (15872-46-5)

Guidance literature:

With potassium hydroxide; In diethylene glycol; at 120 ℃; for 12h;

DOI:10.1021/ja00294a031

Reference yield:

ethyl 4-tetradecyloxybenzoate (40687-17-0) → 4-(tetradecyloxy)benzoic acid (15872-46-5)

Guidance literature:

Acid hydrolysis;

DOI:10.1039/b612065m

upstream raw materials:

methyl 4-tetradecyloxybenzoate

1-Bromotetradecane

4-hydroxy-benzoic acid

ethyl 4-tetradecyloxybenzoate

Downstream raw materials:

4-formylphenyl 4-tetradecyloxybenzoate

1,3-Dicyclohexylurea

4-n-pentylbenzenethio-4'-n-tetradecyloxybenzoate

N,N-Diethyl-4-tetradecyloxy-benzamide

Refernces

• 1、 Thakor, Akshay,Dwivedi, Durgesh J.,Desai, Vipul,Jadeja, Upendra H.,Sharma, Vinay S.,Patel. "Synthesis and characterization of biphenyl-based azo liquid crystals and its optical properties: effect of lateral and tail group". . p. 8 - 26. Retrieved 2021/07/06.
• 2、 Dwivedi, Durgesh J.,Thakor, Akshay,Desai, Vipul,Sharma, Vinay S.,Patel. "Synthesis, mesomorphic properties and biological evolution of calamitic-shaped chalcone-based LCs: effect of lateral and terminal group". . p. 16 - 32. Retrieved 2021/05/26.