(4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Base Information

Chemical Name:(4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene
CAS No.:121625-60-3
Molecular Formula:C₁₅H₁₈O
Molecular Weight:214.307
Hs Code.:
DSSTox Substance ID:DTXSID80153321
Wikidata:Q83020194

Synonyms:(4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene;121625-60-3;CCRIS 7425;DTXSID80153321;(4ABETA,9ALPHA,10ALPHA)-9-METHYL-9,10-EPOXY-TRANS-1,2,3,4,4A,9,10,10A-OCTAHYDROPH ENANTHRENE

Suppliers and Price of (4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 0 raw suppliers

Chemical Property of (4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Chemical Property:

Vapor Pressure:0.00044mmHg at 25°C
Boiling Point:325.3°Cat760mmHg
Flash Point:145.5°C
Density:1.111g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:214.135765193
Heavy Atom Count:16
Complexity:300

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12C(O1)C3CCCCC3C4=CC=CC=C24
Isomeric SMILES:C[C@@]12[C@@H](O1)[C@H]3CCCC[C@@H]3C4=CC=CC=C24

Technology Process of (4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

There total 7 articles about (4abeta,9alpha,10alpha)-9-Methyl-9,10-epoxy-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 121625-58-9
9-methyl-trans-1,2,3,4,4a,10a-hexahydrophenanthrene

: 121625-60-3
(4aβ,10β)-9,10-epoxy-9-methyl-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Guidance literature:: With Perbenzoic acid; sodium hydrogencarbonate; In diethyl ether; at 0 ℃;

Reference yield:

: (4aβ,10β)-t-10-bromo-9-methyl-r-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthren-9-ol

: 121625-60-3
(4aβ,10α)-9,10-epoxy-9-methyl-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Guidance literature:: With potassium tert-butylate; In benzene;

Reference yield:

: 21656-46-2
trans-1,2,3,4,4a,10a-hexahydro-9(10H)-phenanthrenone

: 121625-60-3
(4aβ,10α)-9,10-epoxy-9-methyl-trans-1,2,3,4,4a,9,10,10a-octahydrophenanthrene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) Mg / 1.) Et₂O, 2.) Et₂O, reflux, 4 h; r.t., overnight

2: 3.9 g / p-TsOH / benzene / 0.67 h / Heating

3: 1.5 g / AcNHBr / tetrahydrofuran; H₂O

4: 0.65 g / t-BuOK / benzene

With potassium tert-butylate; toluene-4-sulfonic acid; magnesium; N-bromoacetamide; In tetrahydrofuran; water; benzene;