4,4'-Methylenebis(N,N-diglycidylaniline)

Base Information

• Chemical Name: 4,4'-Methylenebis(N,N-diglycidylaniline)
• CAS No.: 28768-32-3
• Deprecated CAS: 946134-62-9,1882095-52-4
• Molecular Formula: C25H30N2O4
• Molecular Weight: 422.524
• Hs Code.: 29225090
• European Community (EC) Number: 249-204-3
• UNII: 2I8ZB2RX2U
• DSSTox Substance ID: DTXSID0042248
• Nikkaji Number: J39.619B
• Wikidata: Q15725614
• ChEMBL ID: CHEMBL3186444
• Mol file: 28768-32-3.mol

Synonyms:tetraglycidyl-4,4'-methylene dianiline;TGMDA

Chemical Property of 4,4'-Methylenebis(N,N-diglycidylaniline)

Chemical Property:

• Vapor Pressure: 0Pa at 24.85℃
• Refractive Index: n20/D 1.601(lit.)
• Boiling Point: 619.3 °C at 760 mmHg
• PKA: 4.58±0.50(Predicted)
• Flash Point: 113 °C
• PSA: 56.60000
• Density: 1.15 g/cm³
• LogP: 2.48540
• Water Solubility.: 9.2mg/L at 20℃
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 12
• Exact Mass: 422.22055744
• Heavy Atom Count: 31
• Complexity: 512

Purity/Quality:

99% ^*data from raw suppliers

4,4''-Methylenebis(N,N-diglycidylaniline) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,N
• Statements: 43-51/53
• Safety Statements: 36/37-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1C(O1)CN(CC2CO2)C3=CC=C(C=C3)CC4=CC=C(C=C4)N(CC5CO5)CC6CO6

Technology Process of 4,4'-Methylenebis(N,N-diglycidylaniline)

There total 4 articles about 4,4'-Methylenebis(N,N-diglycidylaniline) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C25H34Cl4N2O4 (87017-81-0) → N,N,Ν',N'-tetraglycidyl-4,4'-diaminodiphenylmethane (28768-32-3,31305-94-9)

Guidance literature:

With sodium hydroxide; In water; at 50 ℃; for 1.5h; Temperature;

Reference yield: 95.0%

→ N,N,Ν',N'-tetraglycidyl-4,4'-diaminodiphenylmethane (28768-32-3,31305-94-9)

Guidance literature:

Reference yield: 91.0%

4,4'-diamino diphenyl methane (101-77-9) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → N,N,Ν',N'-tetraglycidyl-4,4'-diaminodiphenylmethane (28768-32-3,31305-94-9)

Guidance literature:

4,4'-diamino diphenyl methane; epichlorohydrin; With lanthanum nitrate; In toluene; at 60 - 85 ℃; under 150.015 - 300.03 Torr;

With benzyltrimethylammonium chloride; sodium hydroxide; In water; toluene; at 60 - 70 ℃; under 150.015 - 375.038 Torr; Pressure; Reagent/catalyst;

upstream raw materials:

4,4'-diamino diphenyl methane

epichlorohydrin

C₂₅H₃₄Cl₄N₂O₄

Downstream raw materials:

C₃₇H₄₂N₄O₆S

Refernces