2-Propenoic acid,3-[(1R,3R,3aR,4S,5S,7aR)-4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl]-2-methyl-,(2E)-rel-(+)-

Base Information

Chemical Name:2-Propenoic acid,3-[(1R,3R,3aR,4S,5S,7aR)-4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl]-2-methyl-,(2E)-rel-(+)-
CAS No.:143052-18-0
Molecular Formula:C24H32 O2
Molecular Weight:352.517
Hs Code.:

Synonyms:2-Propenoicacid, 3-(4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl)-2-methyl-,[1a,3b,3aa,4b(E),5a,7ab]-(+)-; Plakotenin

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Chemical Property of 2-Propenoic acid,3-[(1R,3R,3aR,4S,5S,7aR)-4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl]-2-methyl-,(2E)-rel-(+)-

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MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Propenoic acid,3-[(1R,3R,3aR,4S,5S,7aR)-4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl]-2-methyl-,(2E)-rel-(+)-

There total 18 articles about 2-Propenoic acid,3-[(1R,3R,3aR,4S,5S,7aR)-4-ethyl-2,3,3a,4,5,7a-hexahydro-1,3,7-trimethyl-5-phenyl-1H-inden-4-yl]-2-methyl-,(2E)-rel-(+)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1242061-29-5
C₂₆H₃₆O₂

: 143052-18-0
plakotenin

Guidance literature:: C₂₆H₃₆O₂; With sodium hydroxide; In tetrahydrofuran; methanol; at 40 ℃; for 20h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; methanol; water; Inert atmosphere;
DOI:10.1002/chem.201201585

Reference yield:

: 1432489-24-1
C₂₄H₃₂O

: 143052-18-0
plakotenin

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate dihydrate; dihydrogen peroxide; In water; acetonitrile; at 0 - 20 ℃; for 20h; Inert atmosphere;
DOI:10.1002/chem.201201585

Reference yield:

: 1242061-23-9
(2R,4R,5E,7E)-2,4,6-trimethyl-8-phenylocta-5,7-dien-1-ol

: 143052-18-0
plakotenin

Guidance literature:: Multi-step reaction with 7 steps

1.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / 20 °C / Inert atmosphere

2.2: 3 h / 0 - 20 °C / Inert atmosphere

3.1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

4.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

5.1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / 20 °C / Inert atmosphere

5.2: 0 - 20 °C / Inert atmosphere

6.1: toluene / 20 h / 110 °C / Inert atmosphere

7.1: sodium hydroxide / tetrahydrofuran; methanol / 20 h / 40 °C / Inert atmosphere

7.2: Inert atmosphere

With lithium aluminium tetrahydride; sodium hydride; Dess-Martin periodane; sodium hydroxide; In tetrahydrofuran; methanol; dichloromethane; toluene; mineral oil; 2.2: |Horner-Wadsworth-Emmons Olefination / 5.2: |Horner-Wadsworth-Emmons Olefination;
DOI:10.1002/chem.201201585