Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium

Base Information

Chemical Name:Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium
CAS No.:6730-18-3
Molecular Formula:C16H22N3O10+
Molecular Weight:416.3594
Hs Code.:
DSSTox Substance ID:DTXSID10422774

Synonyms:imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium;DTXSID10422774

Suppliers and Price of Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:11
Exact Mass:416.13051891
Heavy Atom Count:29
Complexity:689

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OC1C(C(C(C(C1OC(=O)C)OC(=O)C)OC(=O)C)OC(=O)C)N=[N+]=N

Technology Process of Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium

There total 52 articles about Imino-(2,3,4,5,6-pentaacetyloxycyclohexyl)iminoazanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 108-24-7
acetic anhydride

: 639079-44-0
(+)-4,5,6-tri-O-acetyl-3-azido-myo-inositol

: 97169-48-7,6730-18-3
(-)-1,2,4,5,6-penta-O-acetyl-3-deoxy-3-azido-myo-inositol

Guidance literature:: With pyridine; for 12h;
DOI:10.1039/b302622a

Reference yield: 98.0%

: 108-24-7
acetic anhydride

: 639079-43-9
(-)-3,4,5-tri-O-acetyl-6-azido-myo-inositol

: 215034-48-3,6730-18-3
(+)-1,2,3,4,5-penta-O-acetyl-6-deoxy-6-azido-myo-inositol

Guidance literature:: With pyridine; for 12h;
DOI:10.1039/b302622a

Reference yield:

: 169529-92-4
(+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol

: 97169-48-7,6730-18-3
(-)-1,2,4,5,6-penta-O-acetyl-3-deoxy-3-azido-myo-inositol

Guidance literature:: Multi-step reaction with 7 steps

1: LiOH / methanol; diethyl ether / 2 h / 0 °C

2: aq. NaN₃; NH₄Cl / 1,2-dimethoxy-ethane; ethanol / 3 h / 0 °C

3: LiOH / diethyl ether; methanol / 2 h / 10 °C

4: 7 g / aq. p-TsOH / 48 h / 20 °C

5: 96 percent / pyridine / 12 h / 20 °C

6: 40 percent / aq. NaIO₄; RuCl₃ / acetonitrile / 0.13 h / ice-cooling

7: 99 percent / pyridine / 12 h

With pyridine; ruthenium trichloride; lithium hydroxide; sodium periodate; sodium azide; ammonium chloride; toluene-4-sulfonic acid; In methanol; 1,2-dimethoxyethane; diethyl ether; ethanol; acetonitrile;
DOI:10.1039/b302622a